[HTML][HTML] Ultrastable glasses: new perspectives for an old problem

C Rodriguez-Tinoco, M Gonzalez-Silveira… - La Rivista del Nuovo …, 2022 - Springer
Ultrastable glasses (mostly prepared from the vapor phase under optimized deposition
conditions) represent a unique class of materials with low enthalpies and high kinetic …

[HTML][HTML] Surface dynamics of glasses

H Tian, Q Xu, H Zhang, RD Priestley, B Zuo - Applied Physics Reviews, 2022 - pubs.aip.org
Two challenging scientific disciplines, ie, the physics of glasses [Anderson, Science 267,
1615 (1995); Kennedy and Norman, Science 309, 75 (2005)] and interface chemistry …

[HTML][HTML] Perspective: Highly stable vapor-deposited glasses

MD Ediger - The Journal of chemical physics, 2017 - pubs.aip.org
This article describes recent progress in understanding highly stable glasses prepared by
physical vapor deposition and provides perspective on further research directions for the …

[HTML][HTML] Surface-mediated formation of stable glasses

P Luo, Z Fakhraai - Annual Review of Physical Chemistry, 2023 - annualreviews.org
Surfaces mediate the formation of stable glasses (SGs) upon physical vapor deposition
(PVD) for a wide range of glass formers. The thermodynamic and kinetic stability of SGs and …

Fast surface diffusion and crystallization of amorphous griseofulvin

C Huang, S Ruan, T Cai, L Yu - The Journal of Physical Chemistry …, 2017 - ACS Publications
Among molecular glasses, griseofulvin (GSF) is one of the fastest crystallizing. To
understand this property, we have measured the surface diffusion in GSF using the method …

Glass dynamics deep in the energy landscape

MD Ediger, M Gruebele, V Lubchenko… - The Journal of …, 2021 - ACS Publications
When a liquid is cooled, progress down the energy landscape is arrested near the glass
transition temperature T g. In principle, lower energy states can be accessed by waiting for …

[HTML][HTML] Amorphous drug-polymer salts

X Yao, AL Neusaenger, L Yu - Pharmaceutics, 2021 - mdpi.com
Amorphous formulations provide a general approach to improving the solubility and
bioavailability of drugs. Amorphous medicines for global health should resist crystallization …

Role of molecular layering in the enhanced mechanical properties of stable glasses

SE Wolf, S Fulco, A Zhang, H Zhao… - The Journal of …, 2022 - ACS Publications
The density, degree of molecular orientation, and molecular layering of vapor-deposited
stable glasses (SGs) vary with substrate temperature (T dep) below the glass-transition …

Molecular orientation for vapor-deposited organic glasses follows rate-temperature superposition: The case of posaconazole

C Bishop, Y Li, MF Toney, L Yu… - The Journal of Physical …, 2020 - ACS Publications
The anisotropic properties of organic glasses produced by physical vapor deposition (PVD)
depend upon substrate temperature and deposition rate. In recent work, it was shown for a …

[HTML][HTML] Design of a homologous series of molecular glassformers

SE Wolf, T Liu, S Govind, H Zhao, G Huang… - The Journal of …, 2021 - pubs.aip.org
We design and synthesize a set of homologous organic molecules by taking advantage of
facile and tailorable Suzuki cross coupling reactions to produce triarylbenzene derivatives …