Alcohol-alcohol cross-coupling enabled by SH2 radical sorting

R Chen, NE Intermaggio, J Xie, JA Rossi-Ashton… - Science, 2024 - science.org
Alcohols represent a functional group class with unparalleled abundance and structural
diversity. In an era of chemical synthesis that prioritizes reducing time to target and …

Alcohols as Alkyl Synthons Enabled by Photoredox-Catalyzed Deoxygenative Activation

T Mandal, S Mallick, M Islam, S De Sarkar - ACS Catalysis, 2024 - ACS Publications
Alcohols are abundant with versatile structural variety and have ample use as pivotal
functional groups in numerous organic processes. Because of their frequent occurrence in …

[HTML][HTML] Recent Developments in the Synthesis of Pharmacological Alkyl Phosphonates

C Xuan, Z Zhu, Z Li, C Shu - Advanced Agrochem, 2024 - Elsevier
Organophosphate analogues are commonly occurring structural features that are widely
present in numerous natural substances, biologically active molecules and modern …

A Hierarchy of Ligands Controls Formation and Reaction of Aryl Radicals in Pd-Catalyzed Ground-State Base-Promoted Coupling Reactions

KF Clark, S Tyerman, L Evans… - Journal of the …, 2023 - ACS Publications
Palladium salts and complexes were tested separately and in the presence of added ligands
as potential sources of aryl radicals in ground-state coupling reactions of aryl halide with …

Photocatalytic C–P bond formation based on the reaction of carbon-centered radicals with phosphides

SY Zhao, YY Huang, SH Deng, ZP Guan… - Organic Chemistry …, 2024 - pubs.rsc.org
Organophosphorus compounds hold significant importance in the fields of materials
science, medicinal chemistry, pesticides and organic synthesis. In particular, phosphonate …

Facile synthesis of alkylphosphonates from 4-alkyl-1, 4-dihydropyridines via photoinduced formal deformylative phosphonylation

H Zhang, Z Cui, J Wang, L Zhu, C Li - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
Here, an unprecedented formal deformylative phosphonylation is disclosed. Under the
catalysis of 1 mol% 1, 2, 3, 5-tetrakis (diphenylamino)-4, 6-dicyanobenzene (4DPAIPN) and …

Photoredox and NHC Enabled Deoxygenative Alcohol Homologation via Formal 1, 2-Addition

S Song, Z Li, L Wang, T Zeng, Q Hu, J Zhu - Organic Letters, 2023 - ACS Publications
A highly efficient photoinduced iron-catalyzed method has been developed for the direct use
of alcohols as surrogates for organometallic reagents in the synthesis of tertiary alcohols …

Breakthrough in phosphonylation of alkyl radicals: Alternative access of alkyl phosphonates

W Zhang, HT Luo, JD Yang - Chem, 2023 - cell.com
Recently, the groups of Aggarwal and Li have independently presented photocatalytic
radical phosphonylations of alkyl radicals with benzhydryl-catechol-phosphites under …

Triphenylphosphine Oxide: A Versatile Covalent Functionality for Carbon Nanotubes

Y Pan, D Baster, D Käch, J Reger… - Angewandte Chemie …, 2024 - Wiley Online Library
Broadening the scope of functionalities that can be covalently bound to single‐walled
carbon nanotubes (SWCNTs) is crucial for enhancing the versatility of this promising …

Photochemical phosphorus-enabled scaffold remodeling of carboxylic acids

Q Peng, MU Hwang, Á Rentería-Gómez, P Mukherjee… - Science, 2024 - science.org
The excitation of carbonyl compounds by light to generate radical intermediates has
historically been restricted to ketones and aldehydes; carboxylic acids have been …