Polymers: Opening doors to future batteries

J Muldoon, CB Bucur, N Boaretto, T Gregory… - Polymer …, 2015 - Taylor & Francis
Research and development of post lithium ion batteries is attracting considerable attention.
While there have been significant advances in understanding the challenges of Li-O2 (air) …

Effect of grain size on the ionic conductivity of a block copolymer electrolyte

M Chintapalli, XC Chen, JL Thelen, AA Teran… - …, 2014 - ACS Publications
A systematic study of the dependence of ionic conductivity on the grain size of a lamellar
block copolymer electrolyte was performed. A freeze-dried mixture of poly (styrene)-block …

Cylinder-gyroid phase transition in a block copolymer electrolyte induced by ionic current

EE Abdo, LS Grundy, MD Galluzzo, WS Loo… - …, 2024 - ACS Publications
We investigate the effect of direct ionic current (dc) on the morphology of a block copolymer
electrolyte in a lithium symmetric cell. We present in situ X-ray scattering and X-ray …

Orientation-Dependent Distortion of Lamellae in a Block Copolymer Electrolyte under DC Polarization

MD Galluzzo, LS Grundy, CJ Takacs, C Cao… - …, 2021 - ACS Publications
Lithium-salt-doped block copolymers have the potential to serve as solid electrolytes in
rechargeable batteries with lithium metal anodes. In this work, we use small-angle X-ray …

Dissolution of Lithium Metal in Poly (ethylene oxide)

MD Galluzzo, DM Halat, WS Loo, SA Mullin… - ACS Energy …, 2019 - ACS Publications
We demonstrate that lithium metal is sparingly soluble in poly (ethylene oxide)(PEO). 7Li
NMR shows that when a PEO sample is placed in contact with lithium metal at elevated …

Reentrant phase behavior and coexistence in asymmetric block copolymer electrolytes

WS Loo, X Jiang, JA Maslyn, HJ Oh, C Zhu… - Soft Matter, 2018 - pubs.rsc.org
It is known that the addition of salts to symmetric block copolymers leads to stabilization of
ordered phases and an increase in domain spacing; both trends are consistent with an …

Block Copolymer Electrolytes with Double Primitive Cubic Structures: Enhancing Solid-State Lithium Conduction via Lithium Salt Localization

H Lee, J Kim, MJ Park - ACS nano, 2025 - ACS Publications
We present a strategy for enhancing Li+ conduction in block copolymer electrolytes by
introducing trace amounts of Li salts into polystyrene-b-poly (ethylene oxide)(PS-b-PEO) …

Dynamic structure and phase behavior of a block copolymer electrolyte under dc polarization

MD Galluzzo, WS Loo, E Schaible, C Zhu… - … Applied Materials & …, 2020 - ACS Publications
An important consideration when designing lithium battery electrolytes for advanced
applications is how the electrolyte facilitates ion transport at fast charge and discharge rates …

Morphology–Transport Coupling and Dissipative Structures in PEO–PS+ LiTFSI Electrolytes In-Operando Conditions

M Tagliazucchi, M Müller - ACS Applied Materials & Interfaces, 2025 - ACS Publications
A Single-Chain-in-Mean-Field (SCMF) algorithm was introduced to study block copolymer
electrolytes in nonequilibrium conditions. This method self-consistently combines a particle …

Ion conduction in microphase-separated block copolymer electrolytes

Y Kambe, CG Arges, S Patel… - The Electrochemical …, 2017 - iopscience.iop.org
by Yu Kambe, Christopher G. Arges, Shrayesh N. Patel, Mark P. Stoykovich, and Paul F.
Nealey molecular architecture consist of two chemically distinct polymer chains that …