The most fundamental concepts in chemistry are structure, energetics, reactivity and their
inter-relationships, which are indispensable for promoting chemistry into a rational science …

Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms | Chemical
Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …

Hydrocarbons, especially saturated hydrocarbons (alkanes), are the main constituents of oil
and natural gas, the feedstocks for chemical industry. Therefore, it is obvious that …

Synthetic methods chemistry has undergoneintense development during the past 50 years.
As a result, nearly every class of organic compound can now be considered as a source of …

Aspects of Methane Chemistry Page 1 Chem. Rev. 1995, 95, 987-1007 987 Aspects of
Methane Chemistry Robert H. Crabtree Department of Chemistry, 225 Prospect Street, Yale …

A series of studies have been conducted by experimental and theoretical methods on the
synthesis, structures, and reactions of Cp* Rh boryl complexes that are likely intermediates …

Kaum eine Stoffklasse läßt sich vielseitiger in der organischen Synthese nutzen als
Carbenkomplexe. Die rasche Entwicklung neuer Synthesemethoden, an denen …

C− H bond activations of benzene and methane by M (η 2-O2CH) 2 (M= Pd or Pt) are
theoretically investigated with density functional theory (DFT), MP2-MP4 (SDQ), and CCSD …

Turning a disadvantage to an advantage: The rather disappointing reactivity of the metal–
nitrogen bond in comparison to the metal–carbon bond resulted in the neglect of …

In this Forum Article, we discuss the use of redox-active pincer-type ligands to enable
multielectron reactivity, specifically nitrene group transfer, at the electron-poor metals …