Hybrid polyoxometalate materials for photo (electro-) chemical applications

JJ Walsh, AM Bond, RJ Forster, TE Keyes - Coordination Chemistry …, 2016 - Elsevier
Polyoxometalate (POM) based supramolecular assemblies have received significant
attention over recent years because of their unique and diverse redox and photochemical …

Covalent multi-component systems of polyoxometalates and metal complexes: Toward multi-functional organic–inorganic hybrids in molecular and material sciences

MP Santoni, GS Hanan, B Hasenknopf - Coordination Chemistry Reviews, 2014 - Elsevier
The rational design and synthesis of organic–inorganic hybrids in molecular and material
sciences lies at the interface of several domains, such as synthetic organic and inorganic …

[图书][B] Electrochemistry of immobilized particles and droplets

F Scholz, U Schröder, R Gulaboski… - 2005 - Springer
Fundamental Electrode Kinetics is represented by treatments of reactions such as O2+ 4H++
4e À Æ 2H2O, still important in the theory of electrocatalysis. As for the cutting edge in …

Synthesis and characterization of open and sandwich-type polyoxometalates reveals visible-light-driven water oxidation via POM-photosensitizer complexes

PE Car, M Guttentag, KK Baldridge, R Alberto… - Green …, 2012 - pubs.rsc.org
The trivacant triruthenium-substituted polyoxometalate α-K6Na [{Ru3O3 (H2O)
Cl2}(SiW9O34)]· 17H2O (1) and two sandwich-type Co-and Ni-containing silicotungstates …

Electrochemical sensing of nitrofurazone on Ru (bpy) 32+ functionalized polyoxometalate combined with graphene modified electrode

S Cai, T Jiao, L Wang, F Wang, Q Chen - Food Chemistry, 2022 - Elsevier
Nitrofurazone is forbidden to be used in aquaculture, but it is often used illegally because of
its good bactericidal effect, and its content in animals is extremely low and difficult to detect …

Oxidation‐responsive polymers: which groups to use, how to make them, what to expect from them (biomedical applications)

E Lallana, N Tirelli - Macromolecular Chemistry and Physics, 2013 - Wiley Online Library
Dramatic physical changes may take place upon the occurrence of oxidation reactions in a
polymer, for example, solubilization or crosslinking. These effects can be used to perform …

Capture of Periodate in a {W18O54} Cluster Cage Yielding a Catalytically Active Polyoxometalate [H3W18O56(IO6)]6− Embedded with High‐Valent Iodine

DL Long, YF Song, EF Wilson… - Angewandte Chemie …, 2008 - Wiley Online Library
The expansion in polyoxometalate (POM) chemistry has accelerated dramatically in recent
years.[1] Much focus has been on the discovery and assembly of new POM clusters [2–6] …

Photocatalysis with polyoxometalates associated to porphyrins under visible light: an application of charge transfer in electrostatic complexes

C Costa-Coquelard, S Sorgues… - The Journal of Physical …, 2010 - ACS Publications
Absorption spectrum of derived Dawson sandwich polyoxometalates (POM)[M4 (H2O) 2
(P2W15O56) 2] n− with n= 16 for M= ZnII, NiII, and n= 12 for M= FeIII have been extended in …

Self-assembly of amphiphilic polyoxometalates for the preparation of mesoporous polyoxometalate-titania catalysts

A Di, J Schmitt, MA Da Silva, KMZ Hossain… - Nanoscale, 2020 - pubs.rsc.org
Amphiphilic polyoxometalate (POM) surfactants were prepared by covalently grafting double
hydrophobic tails with chain lengths C12H25, C14H29, C16H33 or C18H37 onto the …

Enhanced photocurrent production from thin films of Ru (II) metallopolymer/Dawson polyoxotungstate adducts under visible irradiation

JJ Walsh, CT Mallon, AM Bond, TE Keyes… - Chemical …, 2012 - pubs.rsc.org
Thin films of polyoxometalates that are sensitized with a Ru (II) metallopolymer generate
significant photocurrents in the presence of benzyl alcohol and visible light. Significantly, the …