“Green is the color”: An update on ecofriendly aspects of organoselenium chemistry

JB Azeredo, F Penteado, V Nascimento, L Sancineto… - Molecules, 2022 - mdpi.com
Organoselenium compounds have been successfully applied in biological, medicinal and
material sciences, as well as a powerful tool for modern organic synthesis, attracting the …

Applications of oxone® in organic synthesis: an emerging green reagent of modern era

S Alvi, V Jayant, R Ali - ChemistrySelect, 2022 - Wiley Online Library
Presently, the major cornerstone of the research community is to develop green as well as
sustainable protocols involving inexpensive catalysts and/or reagents without the usage of …

Rhodium-Catalyzed Isoquinoline Synthesis Using Vinyl Selenone as Oxidizing Acetylene Surrogate

A Inami, Y Nishii, K Hirano, M Miura - Organic Letters, 2023 - ACS Publications
Isoquinoline is a privileged structure in many bioactive compounds and valuable ligands.
Transition-metal-catalyzed oxidative annulation of imine derivatives has become a …

Selenide-containing soluble polyimides: high refractive index and redox responsiveness

Q Li, S Liu, M Xu, X Pan, N Li, J Zhu, X Zhu - European Polymer Journal, 2020 - Elsevier
Soluble high refractive index polyimides have extensive applications in optical devices due
to their ease of processing and versatility. In this work, selenide-containing polyimides were …

Synthesis and antioxidant activities of N-thiophenyl ebselenamines: a 77 Se {1 H} NMR mechanistic study

M Kumar, VP Singh - New Journal of Chemistry, 2022 - pubs.rsc.org
The step-by-step redox process of bis-[2-phenyl-1, 2-benzisoselenazol-3 (2H)-one-7-yl]
diazene ie azo-bis-ebselen in the presence of PhSH and H2O2 was reported using 77Se …

Modern Synthetic Strategies with Organoselenium Reagents: A Focus on Vinyl Selenones

M Palomba, I Franco Coelho Dias, O Rosati, F Marini - Molecules, 2021 - mdpi.com
In recent years, vinyl selenones were rediscovered as useful building blocks for new
synthetic transformations. This review will highlight these advances in the field of multiple …

A three-component [3+ 2]-cycloaddition/elimination cascade for the synthesis of spirooxindole-pyrrolizines

M Palomba, E De Monte, A Mambrini… - Organic & …, 2021 - pubs.rsc.org
A three-component synthesis of novel spirooxindole-tetrahydropyrrolizines from secondary α-
aminoacids, isatins and vinyl selenones has been disclosed. Products were formed in good …

Synthesis of benzo [b] chalcogenophenes fused to selenophenes via intramolecular electrophilic cyclization of 1, 3-diynes

PS Hellwig, JS Guedes, AM Barcellos… - Organic & …, 2021 - pubs.rsc.org
We describe herein an alternative and transition-metal-free procedure for the access of
benzo [b] chalcogenophenes fused to selenophenes via intramolecular cyclization of 1, 3 …

Rhodium-Catalyzed Direct Vinylene Annulation of 2-Aryloxazolines and Cascade Ring-Opening Using a Vinyl Selenone

J Kitano, Y Nishii, K Hirano, M Miura - Synlett, 2024 - thieme-connect.com
Over the past two decades, transition-metal-catalyzed C–H activation and the subsequent
oxidative cyclization with alkynes or their surrogates has emerged as a powerful synthetic …

Exploring the reactivity of L-tellurocystine, Te-protected tellurocysteine conjugates and diorganodiselenides towards hydrogen peroxide: synthesis and molecular …

A Tripathi, R Deka, RJ Butcher, DR Turner… - New Journal of …, 2022 - pubs.rsc.org
The oxidation reaction of L-tellurocystine,[Te2 {CH2CH (NH3+) COO−} 2](4) with H2O2 in
the presence of HBr resulted in the formation of cyclic, zwitterionic organotellurolate (IV) …