1.1. General Considerations Palladium catalysis is one of the most important synthetic tools
in modern organic synthesis. A particularly attractive synthetic feature of palladium catalysis …

Bernard Shaw's pioneering research1-15 on cyclometalated phosphine-based pincer
complexes has inspired many others. 16-208 Although the first metal complexes with …

Since the first reports in the late 1970s on transition metal complexes containing pincer‐type
ligands—named after the particular coordination mode of these ligands—these systems …

Cyclometalation refers to the transition metal-mediated activation of a CR bond to form a
metallacycle comprising a new metal-carbon σ bond (Scheme 1). 1, 2 Typically, the reaction …

Pincer complexes are formed by the binding of a chemical structure to a metal atom with at
least one carbon-metal bond. Usually the metal atom has three bonds to a chemical …

The application of palladacycles as catalysts for cross-coupling and similar reactions is
reviewed. In the majority of cases palladacycles are likely to serve as a source of highly …

In recent years, the application of membrane technology in homogeneous catalyst recycling
has received widespread attention. This technology offers a solution for the major drawback …

A pincer-Pd complex was utilized in the chemoselective transfer hydrogenation of α, β-
unsaturated ketones using n-BuOH as a hydrogen source and solvent. Good to excellent …

Seit den ersten Berichten über Übergangsmetallkomplexe mit Pinzetten‐Liganden in den
späten siebziger Jahren haben diese Systeme wegen der ungewöhnlichen Eigenschaften …

Currently, gels derived from low-molecular-mass compounds are attracting increasing
interest owing to the simplicity of the gelator molecules, their physical properties, and …