Mechanism of the selective Fe-catalyzed arene carbon–hydrogen bond functionalization

V Postils, M Rodríguez, G Sabenya, A Conde… - ACS …, 2018 - ACS Publications
The complete chemoselective functionalization of aromatic C (sp2)–H bonds of benzene
and alkyl benzenes by carbene insertion from ethyl diazoacetate was unknown until the …

Back-Donation in High-Valent d0 Metal Complexes: Does It Exist? The Case of NbV

G Ciancaleoni, L Belpassi, F Marchetti - Inorganic Chemistry, 2017 - ACS Publications
In the last years, some N-heterocyclic carbene (NHC) complexes of high-valent d0 transition-
metal halides have been structurally characterized, showing a significant short distance …

Substituent effects on the electrochemical, spectroscopic, and structural properties of fischer mono-and biscarbene complexes of chromium (0)

B Van der Westhuizen, PJ Swarts… - Inorganic …, 2013 - ACS Publications
A series of ten ferrocenyl, furyl, and thienyl mono-and biscarbene chromium (0) complexes
were synthesized and characterized spectroscopically and electrochemically. The single …

Tuning the Photophysical Properties of BODIPY Molecules by π‐Conjugation with Fischer Carbene Complexes

GM Chu, A Guerrero‐Martínez… - … A European Journal, 2014 - Wiley Online Library
The synthesis, structure, and photophysical properties of novel BODIPY–Fischer alkoxy‐,
thio‐, and aminocarbene dyads are reported. The BODIPY chromophore is directly attached …

Synthesis, structure and DFT study of asymmetrical NHC complexes of cymantrene derivatives and their application in the dehydrogenative dimerization reaction of …

R Fraser, PH van Rooyen, J de Lange… - Journal of …, 2017 - Elsevier
Asymmetrical NHC complexes of cymantrene and methylcymantrene have been
synthesised through the photochemical substitution of carbonyl ligands in the presence of …

Electrochemical illumination of thienyl and ferrocenyl chromium (0) Fischer carbene complexes

B Van der Westhuizen, PJ Swarts, I Strydom… - Dalton …, 2013 - pubs.rsc.org
A series of ferrocenyl and thienyl mono-and biscarbene chromium (0) complexes 1–6 were
synthesised. The complexes were characterised both spectroscopically and …

Half‐Sandwich Manganese Complex Bearing Fused Oxazoline‐NHC Ligand: Conformational Analysis and Evaluation in Asymmetric Ketone Hydrosilylation

M Cavailles, OA Filippov, V César… - European Journal of …, 2023 - Wiley Online Library
The first manganese complex bearing a chiral N‐heterocyclic carbene (NHC) ligand was
prepared and studied by spectroscopic methods and X‐ray diffraction. While IR …

The Electron Density Distribution in Crystals of η6–[1,4–dihydrospiro(2H–3,1–benzoxazine–2,1′–cyclohexane)]tricarbonylchromium(0): Experiment vs Molecular …

GK Fukin, AV Cherkasov, EV Baranov… - …, 2019 - Wiley Online Library
In this paper we present the results of a high–resolution single crystal X–ray diffraction
experiment of η6–[1, 4–dihydrospiro (2H–3, 1–benzoxazine–2, 1′–cyclohexane)] …

Remote control by π-conjugation of the emissive properties of Fischer carbene-BODIPY dyads

GM Chu, A Guerrero-Martinez… - Inorganic …, 2016 - ACS Publications
The synthesis, structure, and complete characterization of mono-and bimetallic dyads
joining Fischer carbene complexes and BODIPY chromophores are reported. In these …

Unexpected findings in a simple metathesis reaction of europium and ytterbium diiodides with perfluorinated mercaptobenzothiazolates of alkali metals

LI Silantyeva, VA Ilichev, AS Shavyrin… - …, 2020 - ACS Publications
In the search for new f–d luminescent complexes of Eu (II) and Yb (II) the metathesis
reactions of diiodides of these metals with perfluorinated 2-mercaptobenzothiazolates of …