Chiral supramolecular polymers

F García, R Gómez, L Sánchez - Chemical Society Reviews, 2023 - pubs.rsc.org
As an active branch within the field of supramolecular polymers, chiral supramolecular
polymers (SPs) are an excellent benchmark to generate helical structures that can clarify the …

Helical polymers: synthesis, structures, and functions

E Yashima, K Maeda, H Iida, Y Furusho… - Chemical …, 2009 - ACS Publications
The helix is the central structural motif in biological macromolecules, such as DNA and
proteins, and is also the ubiquitous object in nature from microscopic to macroscopic points …

Polymers and the p-block elements

AM Priegert, BW Rawe, SC Serin… - Chemical Society Reviews, 2016 - pubs.rsc.org
A survey of the state-of-the-art in the development of synthetic methods to incorporate p-
block elements into polymers is given. The incorporation of main group elements (groups 13 …

Chirality-responsive helical polymers

E Yashima, K Maeda - Macromolecules, 2008 - ACS Publications
Unique macromolecules that fold into a preferred-handed helical conformation induced by
external chiral stimuli are mainly described in this review. In contrast to small molecular …

Detection and amplification of chirality by helical polymers

E Yashima, K Maeda… - Chemistry–A European …, 2004 - Wiley Online Library
A unique feature of synthetic helical polymers for the detection and amplification of chirality
is briefly described in this article. In sharp contrast to host–guest and supramolecular …

Amplification of molecular asymmetry during the hierarchical self-assembly of foldable azobenzene dyads into nanotoroids and nanotubes

T Saito, T Kajitani, S Yagai - Journal of the American Chemical …, 2022 - ACS Publications
The amplification of molecular asymmetry through self-assembly is a phenomenon that not
only comprehends the origin of homochirality in nature but also produces chiroptically active …

Polymerization of substituted acetylenes and features of the formed polymers

M Shiotsuki, F Sanda, T Masuda - Polymer Chemistry, 2011 - pubs.rsc.org
Progress in the polymerization of substituted acetylenes and the properties and functions of
the formed polymers that have been synthesized in the past several years are surveyed …

A dynamic supramolecular polymer with stimuli-responsive handedness for in situ probing of enzymatic ATP hydrolysis

M Kumar, P Brocorens, C Tonnelé, D Beljonne… - Nature …, 2014 - nature.com
Abstract Design of artificial systems, which can respond to fluctuations in concentration of
adenosine phosphates (APs), can be useful in understanding various biological processes …

Biocatalytic transformations of silicon—The other group 14 element

NS Sarai, BJ Levin, JM Roberts, DE Katsoulis… - ACS Central …, 2021 - ACS Publications
Significant inroads have been made using biocatalysts to perform new-to-nature reactions
with high selectivity and efficiency. Meanwhile, advances in organosilicon chemistry have …

Air-stable (phenylbuta-1, 3-diynyl) palladium (II) complexes: highly active initiators for living polymerization of isocyanides

YX Xue, YY Zhu, LM Gao, XY He, N Liu… - Journal of the …, 2014 - ACS Publications
A family of air-stable (phenylbuta-1, 3-diynyl) palladium (II) complexes were designed and
prepared in a facile synthetic procedure. Their structures were characterized by 1H and 13C …