Modular approach towards functional multimetallic coordination clusters
Polynuclear coordination clusters (PCCs) provide considerable design capabilities towards
various functions based on structural non-rigidity and spin state transitions, optical …
various functions based on structural non-rigidity and spin state transitions, optical …
Molecular Prussian Blue Analogues: From Bulk to Molecules and Low-dimensional Aggregates
M Nihei - Chemistry Letters, 2020 - academic.oup.com
Cyanide-bridged mixed-valence Co-Fe multi-nuclear complexes, 0D molecular Prussian
blue analogues (PBAs), have variable molecular structures and flexible electronic states. In …
blue analogues (PBAs), have variable molecular structures and flexible electronic states. In …
Enlightening the alkali ion role in the photomagnetic effect of FeCo Prussian blue analogues
J Glatz, JR Jiménez, L Godeffroy… - Journal of the …, 2022 - ACS Publications
FeCo Prussian blue analogues of general formula A x Co y [Fe (CN) 6] z are responsive,
non-stoichiometric materials whose magnetic and optical properties can be reversibly …
non-stoichiometric materials whose magnetic and optical properties can be reversibly …
ON/OFF Photo (switching) along with reversible spin-state change and single-crystal-to-single-crystal transformation in a mixed-valence Fe (II) Fe (III) molecular …
A mixed-valence Fe (II) Fe (III) molecular system,{[Fe (pzTp)(CN) 3] 2 [Fe (bik) 2] 2}·[Fe
(pzTp)(CN) 3] 2· 4MeOH (1· 4MeOH)(bik= bis-(1-methylimidazolyl)-2-methanone, pzTp …
(pzTp)(CN) 3] 2· 4MeOH (1· 4MeOH)(bik= bis-(1-methylimidazolyl)-2-methanone, pzTp …
Time-resolved spectroscopy of photoinduced electron transfer in dinuclear and tetranuclear Fe/Co Prussian Blue analogues
J Zimara, H Stevens, R Oswald, S Demeshko… - Inorganic …, 2020 - ACS Publications
The dynamics of the photodriven charge transfer-induced spin transition (CTIST) in two
Fe/Co Prussian Blue Analogues (PBAs) are revealed by femtosecond IR and UV/vis pump …
Fe/Co Prussian Blue Analogues (PBAs) are revealed by femtosecond IR and UV/vis pump …
Spin crossover in the Prussian blue analogue FePt (CN) 6 induced by pressure or X-ray irradiation
The spin state of the Prussian blue analogue FeIIPtIV (CN) 6 is investigated in response to
temperature, pressure, and X-ray irradiation. While cooling to 10 K maintains the high-spin …
temperature, pressure, and X-ray irradiation. While cooling to 10 K maintains the high-spin …
Metal-to-metal electron transfer in a cyanido-bridged {Fe 2 Co 2} square complex followed by X-ray diffraction and absorption techniques
C Mathonière, D Mitcov, E Koumousi… - Chemical …, 2022 - pubs.rsc.org
The switching properties of a cyanido-bridged Fe/Co square molecule were investigated by
single-crystal X-ray diffraction and X-ray absorption spectroscopy at both Fe and Co K …
single-crystal X-ray diffraction and X-ray absorption spectroscopy at both Fe and Co K …
Effect of Ligand Modulation on Metal-to-Metal Electron Transfer in a Series of [Fe2Co2] Molecular Square Complexes
A series of three new cyanide-bridged [FeCo] molecular square complexes, namely,{[Fe
(Tp*)(CN) 3] 2 [Co (L) 2] 2}(BF4) 2· 2DMF (L= bik (1), bik*(2), and vbik (3); Tp*= hydrotris (3 …
(Tp*)(CN) 3] 2 [Co (L) 2] 2}(BF4) 2· 2DMF (L= bik (1), bik*(2), and vbik (3); Tp*= hydrotris (3 …
Anthryl-functionalized cyanide-bridged Fe/Co cubes
Two anthryl-functionalized cyanide-bridged [Fe4Co4] cube complexes,[(pzTp) Fe (CN) 3Co
(TpEtOAn)] 4 [OTf] 4· 8MeCN· 7Et2O (1) and [NEt4] 3 [(pzTp) Fe (CN) 3Co (TpEtOAn)] 4 [OTf] …
(TpEtOAn)] 4 [OTf] 4· 8MeCN· 7Et2O (1) and [NEt4] 3 [(pzTp) Fe (CN) 3Co (TpEtOAn)] 4 [OTf] …
Near room temperature stepwise spin state switching and photomagnetic effect in a mixed-valence molecular square
A two-step thermo-induced spin-state switching was observed in a cyanide-bridged
[Fe2Fe2] molecular square complex,{[Fe (pzTp)(CN) 3] 2 [Fe (L) 2] 2}[Fe (pzTp)(CN) 3] 2 …
[Fe2Fe2] molecular square complex,{[Fe (pzTp)(CN) 3] 2 [Fe (L) 2] 2}[Fe (pzTp)(CN) 3] 2 …