Activation of robust bonds by carbonyl complexes of Mn, Fe and Co

MR Radzhabov, NP Mankad - Chemical Communications, 2023 - pubs.rsc.org
Metal carbonyl complexes possess among the most storied histories of any compound class
in organometallic chemistry. Nonetheless, these old dogs continue to be taught new tricks. In …

Photochemical H 2 activation by an Zn–Fe heterometallic: a mechanistic investigation

M Perez-Jimenez, MR Crimmin - Chemical Science, 2024 - pubs.rsc.org
Addition of H2 to a Zn–Fe complex was observed to occur under photochemical conditions
(390 or 428 nm LED) and leads to the formation of a heterometallic dihydride complex. The …

Ni-Catalyzed Cyanation of (Hetero) aryl Halides with Acetonitrile as Cyano Source

MS Ahmad, B Zeng, R Qasim, D Zheng, Q Zhang… - ACS …, 2024 - ACS Publications
We present a highly efficient method for cyanating challenging substrates with a specific
focus on aryl fluorides. This innovative methodology has been successfully expanded to …

Catalytic Synthesis and Cyclometalation of (4-Ferrocenylphenyl) pyridines

P Harmach, BN Baumann, J Schulz, I Císařová… - …, 2024 - ACS Publications
Metal-catalyzed [2+ 2+ 2] cyclization reactions are powerful tools for the preparation of
(hetero) aromatic compounds. However, they have rarely been applied in ferrocene …