Hydroformylation in the Realm of Scents

EV Gusevskaya, J Jiménez‐Pinto, A Börner - ChemCatChem, 2014 - Wiley Online Library
Abstract Metal (Co, Rh, Pt/Sn)‐catalyzed homogeneous hydroformylation reactions produce
aldehydes, acetals, and alcohols, respectively, which are important aroma compounds that …

Isomerization–hydroformylation tandem reactions

M Vilches-Herrera, L Domke, A Börner - ACS Catalysis, 2014 - ACS Publications
The metal-catalyzed isomerization–hydroformylation tandem reaction is of great importance
for the production of linear aldehydes starting from internal olefins, but also, the shift of the …

Rh catalyzed multicomponent tandem and one-pot reactions under hydroformylation conditions

BP Bondžić - Journal of Molecular Catalysis A: Chemical, 2015 - Elsevier
The hydroformylation reaction represents one of the most important metal catalyzed bulk
chemical manufacturing processes today. However, tremendous progress towards more …

Anisole: a further step to sustainable hydroformylation

FG Delolo, EN dos Santos, EV Gusevskaya - Green Chemistry, 2019 - pubs.rsc.org
Hydroformylation, also known as the “oxo” process, is a major industrial process that
employs rhodium or cobalt catalysts in solution; therefore the solvent of this process is a …

Catalytic multi-step continuous-flow processes for scalable transformation of eugenol into potential fragrances

FMS Rodrigues, V Masliy, MFC Silva, AP Felgueiras… - Catalysis Today, 2023 - Elsevier
Catalytic multi-step processes were optimized and developed under continuous-flow
conditions, to transform eugenol into potential new fragrances. One approach consisted in …

Hydroformylation of biomass-based hydroxyolefins in eco-friendly solvents: New fragrances from myrtenol and nopol

FG Delolo, KCB Oliveira, EN dos Santos… - Molecular …, 2019 - Elsevier
The hydroformylation of the naturally occurring hydroxyolefins (1R)-(–)-myrtenol (1) and (1R)-
(–)-nopol (2) was performed employing a rhodium (I)/bulky phosphite catalytic system. Both …

Hydroxymethylation of unsaturated hydrocarbons with CO2: An overview

X Wang, W Ping, AG Ebadi, S Majedi, Z Hossaini… - Journal of CO2 …, 2021 - Elsevier
The objective of this review is to summarize recent progress and advances in the synthesis
of hydroxymethyl-alcohols through the direct hydroxymethylation of unsaturated …

Co-catalysis of a bi-functional ligand containing phosphine and Lewis acidic phosphonium for hydroformylation–acetalization of olefins

YQ Li, P Wang, H Liu, Y Lu, XL Zhao, Y Liu - Green Chemistry, 2016 - pubs.rsc.org
A novel ionic bi-functional ligand of L2 containing a phosphine and a Lewis acidic
phosphonium with I− as the counter-anion was prepared and fully characterized. The …

Tandem hydroformylation–acetalization with a ruthenium catalyst immobilized in ionic liquids

J Norinder, C Rodrigues, A Boerner - Journal of Molecular Catalysis A …, 2014 - Elsevier
For the first time, a ruthenium catalyzed hydroformylation–acetalization reaction of olefins is
presented. The tandem reaction proceeds well with 1, 2-or 1, 3-diols, trapping the …

Rhodium‐Catalyzed Chemo‐, Regio‐and Enantioselective Hydroformylation of Cyclopropyl‐Functionalized Trisubstituted Alkenes

S Li, D Zhang, R Zhang, ST Bai… - Angewandte Chemie …, 2022 - Wiley Online Library
The first rhodium‐catalyzed highly chemo‐, regio‐and enantioselective hydroformylation of
cyclopropyl‐functionalized trisubstituted alkenes affording useful chiral cyclopropyl entities …