Sulfur-protected enantiopure P-chiral 1-phosphanorbornane silyl ethers 5a, b are obtained
in high yields via the reaction of the hydroxy group of P-chiral 1-phosphanorbornane alcohol …

The heavier main group multiple bonds offer an effective tool for small molecule activation.
Transient 2H‐phosphinidole working as a reactive phosphadiene system undergoes …

The reactive P− N bond in a racemic mixture of endo‐1‐phospha‐2‐azanorbornene
(PAN)(RP/SP)‐endo‐1 is readily cleaved with enantiomerically pure lithium alkoxides …

A convenient synthesis of enantiopure mixed donor phosphine–phosphite ligands has been
developed incorporating P-stereogenic phosphanorbornane and axially chiral bisnaphthols …

The phospha-Diels–Alder reaction between 2H-phospholes and arylallenes affords 6-
methylene-1-phosphanorbornenes in high yields with excellent regioselectivity. This Diels …

The reactive PN bond in 1-phospha-2-azanorbornenes is readily cleaved by simple alcohols
to afford P-chiral 2, 3-dihydrophosphole derivatives as a racemic mixture. The isolation of …

A straightforward synthesis of P-chiral polycyclic phosphines by an asymmetric Diels–Alder
reaction of 1-alkyl-1, 2-diphospholes and (5R)-(L-menthyloxy)-2 (5H)-furanone (MOxF) is …

The unprecedented phospha‐aza‐Diels–Alder reaction between an activated electron‐poor
imine and 2H‐phospholes yields 1‐phospha‐2‐azanorbornenes in a highly chemoselective …

Abstract Treatment of N, C, N‐chelated organopnictogen (I) compounds ArE (1–3)(Ar= 2, 6‐
(RN= CH) 2C6H3, E/R= As/Dmp (1), Sb/tBu (2), and Bi/tBu (3), where Dmp= 2, 6‐Me2C6H3) …

Aromatic heteroarenes are essential components of numerous valuable molecules. Herein
we present a simple and effective route to access aromatic 1 H-1, 2-azaphospholes and …