Polymers with advanced architectures as emulsifiers for multi-functional emulsions

M Hu, TP Russell - Materials Chemistry Frontiers, 2021 - pubs.rsc.org
Emulsions have wide applications in the food, cosmetics, and pharmaceutical industries.
Emulsions stabilized with polymers having different architectures, such as linear diblock and …

Molecular brush surfactants: versatile emulsifiers for stabilizing and structuring liquids

B Wang, T Liu, H Chen, B Yin, Z Zhang… - Angewandte Chemie …, 2021 - Wiley Online Library
Using amphiphilic molecular brushes to stabilize emulsions usually requires the synthesis of
specific side chains, which can be a time‐consuming and difficult challenge to meet. By …

Bottlebrush Networks: A Primer for Advanced Architectures

BR Clarke, CL Witt, M Ilton, AJ Crosby… - Angewandte …, 2024 - Wiley Online Library
Bottlebrush networks (BBNs) are an exciting new class of materials with interesting physical
properties derived from their unique architecture. While great strides have been made in our …

In-situ grafting of dextran on oil body associated proteins at the oil–water interface through maillard glycosylation: Effect of dextran molecular weight

Y Niu, Y Li, Y Qiao, F Li, D Peng, W Shen, W Jin… - Food …, 2024 - Elsevier
Oil bodies, which are lipid-storage organelles in plant seeds, are stabilized by monolayer of
phospholipids and oil body associated proteins (OBAPs). OBAPs have unique interfacial …

Oil-in-Water Emulsions Stabilized by Hydrophilic Homopolymers

S Karishma, K Rajvanshi, H Kumar, MG Basavaraj… - Langmuir, 2023 - ACS Publications
Most of the polymeric emulsifiers have diblock and triblock copolymer architecture
containing hydrophilic and hydrophobic domains. In this work, we show that hydrophilic …

Amphiphilic Heterografted Molecular Bottlebrushes with Tertiary Amine‐Containing Side Chains as Efficient and Robust pH‐Responsive Emulsifiers

MT Kelly, Z Chen, TP Russell, B Zhao - Angewandte Chemie, 2023 - Wiley Online Library
By combining the unique characteristics of molecular bottlebrushes (MBBs) and the
properties of stimuli‐responsive polymers, we show that MBBs with randomly grafted poly (n …

Rheology of graphene oxide stabilized Pickering emulsions

SM Cui, S Hashmi, WQ Li, S Handschuh-Wang, CT Zhu… - Soft Matter, 2023 - pubs.rsc.org
Pickering emulgels stabilized by graphene oxide (GO) with didodecyldimethylammonium
bromide (DDAB) as an auxiliary surfactant and liquid paraffin as the oil phase have proved …

Colloidal Jamming by Interfacial Self‐Assembled Polymers: A Robust Route for Ultrahigh Efficient Encapsulation

Q Huo, Y Gao, W Wu, S Hu, Z Zhang… - Angewandte Chemie …, 2022 - Wiley Online Library
The control of cargo phase‐transfer is of interest for many applications in science and
technology. Herein, we report a simple, versatile and robust method to block the phase …

Bottlebrush Block Copolymers at the Interface of Immiscible Liquids: Adsorption and Lateral Packing

HG Seong, Z Jin, Z Chen, M Hu, T Emrick… - Journal of the …, 2024 - ACS Publications
Amphiphilic bottlebrush block copolymers (BBCPs), having a hydrophilic bottlebrush
polymer (BP) linked covalently to a hydrophobic BP, were found to segregate to liquid–liquid …

pH-dependent interfacial tension and dilatational modulus synergism of oil-soluble fatty acid and water-soluble cationic surfactants at the oil/water interface

TL Hsieh, S Law, S Garoff, RD Tilton - Langmuir, 2021 - ACS Publications
While the concept of interfacial tension synergism in surfactant mixtures is well established,
little attention has been paid to the possibility of synergistic effects on the interfacial rheology …