Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Catalysis of alloys: classification, principles, and design for a variety of materials and reactions

Y Nakaya, S Furukawa - Chemical Reviews, 2022 - ACS Publications
Alloying has long been used as a promising methodology to improve the catalytic
performance of metallic materials. In recent years, the field of alloy catalysis has made …

Liquid‐metal‐assisted programmed galvanic engineering of core–shell nanohybrids for microwave absorption

B Zhao, Y Du, H Lv, Z Yan, H Jian… - Advanced Functional …, 2023 - Wiley Online Library
Core–shell nanostructures have received widespread attention because of their potential
usage in various technological and scientific fields. However, they still face significant …

Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Materials-driven soft wearable bioelectronics for connected healthcare

S Gong, Y Lu, J Yin, A Levin, W Cheng - Chemical Reviews, 2024 - ACS Publications
In the era of Internet-of-things, many things can stay connected; however, biological
systems, including those necessary for human health, remain unable to stay connected to …

Preparation of Au@Pd Core–Shell Nanorods with fcc-2H-fcc Heterophase for Highly Efficient Electrocatalytic Alcohol Oxidation

X Zhou, Y Ma, Y Ge, S Zhu, Y Cui, B Chen… - Journal of the …, 2021 - ACS Publications
Controlled construction of bimetallic nanostructures with a well-defined heterophase is of
great significance for developing highly efficient nanocatalysts and investigating the …

Controllable constructing janus homologous heterostructures of transition metal alloys/sulfides for efficient oxygen electrocatalysis

Q Lu, H Wu, X Zheng, Y Cao, J Li… - Advanced Energy …, 2022 - Wiley Online Library
Constructing novel heterostructures is an effective way for enhancing the oxygen
electrocatalytic properties of the catalysts. In this work, a class of Janus homologous …

Synthesis of core/shell nanocrystals with ordered intermetallic single-atom alloy layers for nitrate electroreduction to ammonia

Q Gao, B Yao, HS Pillai, W Zang, X Han, Y Liu… - Nature …, 2023 - nature.com
Structurally ordered intermetallic nanocrystals (NCs) and single-atom catalysts (SACs) are
two emerging catalytic motifs for sustainable chemical production and energy conversion …

Conjugated dual size effect of core-shell particles synergizes bimetallic catalysis

X Zhang, Z Sun, R Jin, C Zhu, C Zhao, Y Lin… - Nature …, 2023 - nature.com
Core-shell bimetallic nanocatalysts have attracted long-standing attention in heterogeneous
catalysis. Tailoring both the core size and shell thickness to the dedicated geometrical and …

Coupling of nanocrystal hexagonal array and two-dimensional metastable substrate boosts H2-production

Z Fan, F Liao, Y Ji, Y Liu, H Huang, D Wang… - Nature …, 2022 - nature.com
Designing well-ordered nanocrystal arrays with subnanometre distances can provide
promising materials for future nanoscale applications. However, the fabrication of aligned …