Iron catalysis in organic synthesis
I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …
June 2014 and represents a comprehensive update of a previous article published by Bolm …
Transition-metal-catalyzed ortho-selective C–H functionalization reactions of free phenols
Phenols are important readily available chemical feedstocks and versatile synthetic building
blocks for diverse synthetic transformations. Their motifs are prevalent in a diverse array of …
blocks for diverse synthetic transformations. Their motifs are prevalent in a diverse array of …
Iron-catalyzed carbonylation-peroxidation of alkenes with aldehydes and hydroperoxides
A three-component reaction of alkenes, aldehydes, and hydroperoxides catalyzed by FeCl2
to β-peroxy ketones has been achieved. This three-component reaction can be also applied …
to β-peroxy ketones has been achieved. This three-component reaction can be also applied …
Significant Enhancement in the Efficiency and Selectivity of Iron‐Catalyzed Oxidative Cross‐Coupling of Phenols by Fluoroalcohols
E Gaster, Y Vainer, A Regev, S Narute… - Angewandte Chemie …, 2015 - Wiley Online Library
Significant enhancement of both the rate and the chemoselectivity of iron‐catalyzed
oxidative coupling of phenols can be achieved in fluorinated solvents, such as 1, 1, 1, 3, 3, 3 …
oxidative coupling of phenols can be achieved in fluorinated solvents, such as 1, 1, 1, 3, 3, 3 …
Recent advances in the catalytic synthesis of α-ketoamides
α-Ketoamides and their derivatives are key constituents of natural products, biologically
relevant molecules, drug and drug candidates, and functional materials. Further, they are …
relevant molecules, drug and drug candidates, and functional materials. Further, they are …
I2-Promoted Selective Oxidative Cross-Coupling/Annulation of 2-Naphthols with Methyl Ketones: A Strategy To Build Naphtho[2,1-b]furan-1(2H)-ones with a …
A highly efficient and selective molecular iodine-promoted oxidative cross-
coupling/annulation between 2-naphthols and methyl ketones has been realized. The …
coupling/annulation between 2-naphthols and methyl ketones has been realized. The …
Copper-catalyzed ortho-acylation of phenols with aryl aldehydes and its application in one-step preparation of xanthones
In the presence of triphenylphosphine, copper (II) chloride can catalyze an intermolecular
ortho-acylation reaction of phenols with aryl aldehydes. The reaction proceeds smoothly …
ortho-acylation reaction of phenols with aryl aldehydes. The reaction proceeds smoothly …
Iron fluoride: the most efficient catalyst for one-pot synthesis of 4H-pyrimido [2, 1-b] benzothiazoles under solvent-free conditions
A new iron fluoride assisted convenient and efficient strategy for the preparation of 4H-
pyrimido [2, 1-b] benzothiazoles derivatives in solvent-free media is described. The …
pyrimido [2, 1-b] benzothiazoles derivatives in solvent-free media is described. The …
Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions?–A Fruitful Interplay Anyway: Part 2. Radical Catalysis by Group 8 …
U Jahn - Radicals in Synthesis III, 2012 - Springer
This review summarizes the current status of transition metal catalyzed reactions involving
radical intermediates in organic chemistry. This part focuses on radical-based methods …
radical intermediates in organic chemistry. This part focuses on radical-based methods …
Iron-catalyzed oxidative direct α-C–H bond functionalization of cyclic ethers: selective C–O bond formation in the presence of a labile aldehyde group
Iron catalyzed oxidative coupling of salicylaldehydes with cyclic ethers proceeded through
the direct α-C–H functionalization of ethers, forming the corresponding acetals in moderate …
the direct α-C–H functionalization of ethers, forming the corresponding acetals in moderate …