Sodium periodate mediated oxidative transformations in organic synthesis

A Sudalai, A Khenkin, R Neumann - Organic & Biomolecular …, 2015 - pubs.rsc.org
The investigation of new oxidative transformations for the synthesis of carbon–heteroatom
and heteroatom–heteroatom bonds is of fundamental importance in the synthesis of …

Electrophilic Iodination of Organic Compounds Using Elemental Iodine or Iodides: Recent Advances 2008–2021: Part I

N Ajvazi, S Stavber - compounds, 2022 - mdpi.com
The iodination of organic compounds is of great importance in synthetic organic chemistry. It
opens comprehensive approaches for the synthesis of various biologically active …

Benzylic C–H azidation using the Zhdankin reagent and a copper photoredox catalyst

PTG Rabet, G Fumagalli, S Boyd, MF Greaney - Organic letters, 2016 - ACS Publications
An azidation method for C–N bond formation at benzylic C–H positions is described using
copper-catalyzed visible light photochemistry and the Zhdankin azidoiodinane reagent. The …

γ,δ,ε-C(sp3)–H Functionalization through Directed Radical H-Abstraction

T Liu, TS Mei, JQ Yu - Journal of the American Chemical Society, 2015 - ACS Publications
Aliphatic amides are selectively functionalized at the γ-and δ-positions through directed
radical 1, 5 and 1, 6 H-abstractions, respectively. The initially formed γ-or δ-lactams are …

Copper-catalyzed amination of primary benzylic C− H bonds with primary and secondary sulfonamides

DA Powell, H Fan - The Journal of Organic Chemistry, 2010 - ACS Publications
A room-temperature, copper-catalyzed amination of primary benzylic C− H bonds with
primary and secondary sulfonamides is described. The reaction is applicable to the coupling …

Transition-metal-free oxidative aliphatic C–H azidation

X Zhang, H Yang, P Tang - Organic letters, 2015 - ACS Publications
The first example of a practical and selective azidation of unactivated aliphatic C–H bonds
with easily handled sulfonyl azides as azide source without the use of transition metals has …

Ag‐Promoted Azido‐Carbocyclization of Activated Alkenes via C H Bond Cleavage

Y Yuan, T Shen, K Wang, N Jiao - Chemistry–An Asian Journal, 2013 - Wiley Online Library
Nitrogen-containing compounds, which are found in a wide range of natural products,
material science, and pharmaceuticals, have attracted the interest of many chemists due to …

A Facile Electrochemical Strategy for the Azidation of Benzylic C(sp3)−H Bonds

G He, Y Li, S Zhou, X Yang, A Shang… - European Journal of …, 2022 - Wiley Online Library
We report a direct azidation of benzylic C (sp3)− H bonds via an electrochemical process,
which use cheap and durable graphite plates as electrodes, without any external oxidants or …

Vicinal, Double C–H Functionalization of Alcohols via an Imidate Radical-Polar Crossover Cascade

AF Prusinowski, RK Twumasi… - Journal of the …, 2020 - ACS Publications
A double functionalization of vicinal sp 3 C–H bonds has been developed, wherein a β
amine and γ iodide are incorporated onto an aliphatic alcohol in a single operation. This …

NaIO4–NaN3-mediated diazidation of styrenes, alkenes, benzylic alcohols, and aryl ketones

DA Kamble, PU Karabal, PV Chouthaiwale… - Tetrahedron Letters, 2012 - Elsevier
Sodium periodate and sodium azide combination has been found to be an excellent reagent
system suitable for the direct diazidation of styrenes, alkenes, benzylic alcohols, and aryl …