Heteroarenes containing oxygen, nitrogen, and/or sulfur are important in numerous aspects
of chemistry and everyday life. C–H functionalization of heteroarenes represents the fastest …

Decarboxylation strategy has been emerging as a powerful tool for the synthesis of fluorine-
containing organic compounds that play important roles in various fields such as …

Reforming sustainable 3d-metal-based visible light catalytic platforms for inert bulk chemical
activation is highly desirable. Herein, we demonstrate the use of a Brønsted acid to unlock …

Trifluoroacetates are the most abundant and accessible sources of trifluoromethyl groups,
which are key components in pharmaceuticals and agrochemicals. The generation of …

The trifluoromethyl (CF3) group is an essential moiety in medicinal chemistry due to its
unique physicochemical properties. While trifluoroacetic acid (TFA) is an inexpensive and …

A selection of perfluoroalkylation reactions of aliphatic substrates that display
methodological and synthetic amplitude will be studied, giving examples of their …

An electrochemical approach has been leveraged to underpin a new conceptual platform for
dehydration reactions, which has been demonstrated in the context of esterification. Esters …

Development of novel functional materials for effective isomer separation is of great
significance in environmental science, chemical industry, and life science due to the different …

The evaluation of the pentafluorocyclopropyl group as a chemotype in crop protection and
medicinal chemistry has been hampered in the past by the lack of suitable methodologies …

Molecular Ag (II) complexes are superoxidizing photoredox catalysts capable of generating
radicals from redox-reticent substrates. In this work, we exploited the electrophilicity of Ag (II) …