The hallmark of nucleophilic phosphine catalysis is the initial nucleophilic addition of a
phosphine to an electrophilic starting material, producing a reactive zwitterionic …

Asymmetric phosphine catalysis showcasing remarkable progress over the past two
decades has emerged as a key synthetic platform for the creation of molecular frameworks …

Nucleophilic phosphine catalysis is a practical and powerful tool for the synthesis of various
heterocyclic compounds with the advantages of environmentally friendly, metal-free, and …

Chiral monophosphorus ligands are playing an important role for the recent advances in
asymmetric catalysis. This review summarizes the latest progress in various asymmetric …

In this review, we summarize some of the most recent advances in the construction of cyclic
compounds from the annulation of Morita–Baylis–Hillman (MBH) adducts, which have …

Asymmetric reactions merging organocatalysis and metal catalysis significantly broaden the
scope of organic synthesis. Nevertheless, the accomplishment of stereoselective …

An efficient synthetic protocol for the selective construction of spiro [indoline-3, 5′-pyrrolo
[3, 4-b] azepines] and spiro [indoline-3, 3′-pyrroles] via a cycloaddition reaction of α, β …

A novel phosphine‐catalyzed, highly enantioselective umpolung addition of trifluoromethyl
ketimines to Morita–Baylis–Hillman carbonates was developed and it provides facile access …

A Lewis-base-catalyzed enantioselective [3+ 3] annulation reaction of Morita–Baylis–
Hillman (MBH) carbonates with α-arylidene pyrazolinones is described, affording the …

The Lewis-base-catalyzed enantioselective formal [4+ 2] annulation reaction of o-acylamino-
aryl MBH carbonates and electron-deficient olefins was developed. Tetrahydroquinolines …