Bio-based valorization of lignin-derived phenolic compounds: a review

L Martínková, M Grulich, M Pátek, B Křístková… - Biomolecules, 2023 - mdpi.com
Lignins are the most abundant biopolymers that consist of aromatic units. Lignins are
obtained by fractionation of lignocellulose in the form of “technical lignins”. The …

Decarboxylative Bromooxidation of Indoles by a Vanadium Haloperoxidase

CE Wells, LPT Ramos, LJ Harstad, LZ Hessefort… - ACS …, 2023 - ACS Publications
Halooxindoles are versatile building blocks for the construction of complex oxindole-
containing targets of biological importance. Despite their synthetic value, catalytic methods …

Enhancing the ROS Sensitivity of a Responsive Supramolecular Hydrogel Using Peroxizyme Catalysis

I Piergentili, T Hilberath, B Klemm, F Hollmann… - …, 2023 - ACS Publications
Hydrogels that can disintegrate upon exposure to reactive oxygen species (ROS) have the
potential for targeted drug delivery to tumor cells. In this study, we developed a …

Decarboxylative halogenation of indoles by vanadium haloperoxidases

LJ Harstad, CE Wells, HJ Lee, LPT Ramos… - Chemical …, 2023 - pubs.rsc.org
Halogenated heteroarenes are key building blocks across numerous chemical industries.
Here, we report that vanadium haloperoxidases are capable of producing 3-haloindoles …

Synthesis of Enantiopure Vicinal Halohydrins Using a Sequence of Haloperoxidase and Lipase

E De Marchi, T Hilberath, C Zippilli… - Advanced Synthesis …, 2024 - Wiley Online Library
Vicinal halohydrins are key building blocks to produce bioactive molecules and drugs,
especially if they can be obtained in enantiomerically pure form. In this study, we present a …

Blue‐LED Synthesis of Pummerer's Ketones by Peroxidase‐Lignin‐Catalyzed Oxidative Coupling of Substituted Phenols

D Piccinino, N Ceccotti Vlas… - European Journal of …, 2023 - Wiley Online Library
Pummerer's ketones resembling the tricyclic scaffold of bioactive natural substances were
synthesized by blue‐LED driven Horseradish Peroxidase oxidative coupling of substituted …

[HTML][HTML] Recent Advances in Photoenzymatic Catalysis

C Xiang - International Journal of Organic Chemistry, 2024 - scirp.org
Photoenzymatic catalysis has become an emerging field in organic synthetic chemistry that
provides eco-friendly alternatives to traditional methods. This comprehensive review …