Molecular and heterogeneous water oxidation catalysts: recent progress and joint perspectives

J Li, CA Triana, W Wan, DPA Saseendran… - Chemical Society …, 2021 - pubs.rsc.org
The development of reliable water oxidation catalysts (WOCs) is essential for implementing
artificial photosynthesis on a large technological scale. WOC research has evolved into two …

Structural transformations of solid electrocatalysts and photocatalysts

L Liu, A Corma - Nature Reviews Chemistry, 2021 - nature.com
Heterogeneous catalysts often undergo structural transformations when they operate under
thermal reaction conditions. These transformations are reflected in their evolving catalytic …

Unraveling Sequential Oxidation Kinetics and Determining Roles of Multi-Cobalt Active Sites on Co3O4 Catalyst for Water Oxidation

W Kang, R Wei, H Yin, D Li, Z Chen… - Journal of the …, 2023 - ACS Publications
The multi-redox mechanism involving multi-sites has great implications to dictate the
catalytic water oxidation. Understanding the sequential dynamics of multi-steps in oxygen …

Mechanism of oxygen evolution catalyzed by cobalt oxyhydroxide: cobalt superoxide species as a key intermediate and dioxygen release as a rate-determining step

A Moysiadou, S Lee, CS Hsu, HM Chen… - Journal of the American …, 2020 - ACS Publications
The oxygen evolution reaction (OER) is the performance-limiting half reaction of water
splitting, which can be used to produce hydrogen fuel using renewable energies. Whereas a …

Facet-dependent active sites of a single Cu2O particle photocatalyst for CO2 reduction to methanol

YA Wu, I McNulty, C Liu, KC Lau, Q Liu, AP Paulikas… - Nature Energy, 2019 - nature.com
Atomic-level understanding of the active sites and transformation mechanisms under
realistic working conditions is a prerequisite for rational design of high-performance …

Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution

A Grimaud, O Diaz-Morales, B Han, WT Hong… - Nature …, 2017 - nature.com
Understanding how materials that catalyse the oxygen evolution reaction (OER) function is
essential for the development of efficient energy-storage technologies. The traditional …

Unified structural motifs of the catalytically active state of Co (oxyhydr) oxides during the electrochemical oxygen evolution reaction

A Bergmann, TE Jones, E Martinez Moreno… - Nature Catalysis, 2018 - nature.com
Efficient catalysts for the anodic oxygen evolution reaction (OER) are critical for
electrochemical H2 production. Their design requires structural knowledge of their …

Tracking catalyst redox states and reaction dynamics in Ni–Fe oxyhydroxide oxygen evolution reaction electrocatalysts: the role of catalyst support and electrolyte pH

M Görlin, J Ferreira de Araújo… - Journal of the …, 2017 - ACS Publications
Ni–Fe oxyhydroxides are the most active known electrocatalysts for the oxygen evolution
reaction (OER) in alkaline electrolytes and are therefore of great scientific and technological …

O–O bond formation in ruthenium-catalyzed water oxidation: single-site nucleophilic attack vs. O–O radical coupling

DW Shaffer, Y Xie, JJ Concepcion - Chemical Society Reviews, 2017 - pubs.rsc.org
In this review we discuss at the mechanistic level the different steps involved in water
oxidation catalysis with ruthenium-based molecular catalysts. We have chosen to focus on …

Photoelectrochemical Reduction of CO2 Coupled to Water Oxidation Using a Photocathode with a Ru(II)–Re(I) Complex Photocatalyst and a CoOx/TaON …

G Sahara, H Kumagai, K Maeda, N Kaeffer… - Journal of the …, 2016 - ACS Publications
Photoelectrochemical CO2 reduction activity of a hybrid photocathode, based on a Ru (II)–
Re (I) supramolecular metal complex photocatalyst immobilized on a NiO electrode (NiO …