Glycans, carbohydrate molecules in the realm of biology, are present as biomedically
important glycoconjugates and a characteristic aspect is that their structures in many …

This review is the counterpart of a 2018 Chemical Reviews article (Adero, PO; Amarasekara,
H.; Wen, P.; Bohé, L.; Crich, D. Chem. Rev. 2018, 118, 8242–8284) that examined the …

A critical review of the state-of-the-art evidence in support of the mechanisms of
glycosylation reactions is provided. Factors affecting the stability of putative oxocarbenium …

Substrate side chain conformation impacts reactivity during glycosylation and glycoside
hydrolysis and is restricted by many glycosidases and glycosyltransferases during catalysis …

Carbohydrate chemistry is an essential component of the glycosciences and is fundamental
to their progress. This Perspective takes the position that carbohydrate chemistry, or …

An overview of recent advances in glycosylation with particular emphasis on mechanism is
presented. The mounting evidence for both the existence of glycosyl oxocarbenium ions as …

A practical approach has been developed to convert glucals and rhamnals into
disaccharides or glycoconjugates with high α‐selectivity and yields (77–97%) using a trans …

Sialic acid is an important component of cell surface glycans, which are responsible for
many vital body functions and should therefore be thoroughly studied to understand their …

The stereoselective synthesis of oligosaccharides remains one of the biggest challenges in
carbohydrate chemistry. Many factors, including reaction conditions and the type of glycosyl …

Pseudaminic acid is an amino deoxy sialic acid whose glycosides are essential components
of many pathogenic Gram-negative bacterial cell walls including those from Pseudomonas …