[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time

A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

Lanthanide molecular cluster-aggregates as the next generation of optical materials

DA Gálico, CMS Calado, M Murugesu - Chemical Science, 2023 - pubs.rsc.org
In this perspective, we provide an overview of the recent achievements in luminescent
lanthanide-based molecular cluster-aggregates (MCAs) and illustrate why MCAs can be …

Toward opto-structural correlation to investigate luminescence thermometry in an organometallic Eu (II) complex

RM Diaz-Rodriguez, DA Gálico… - Journal of the …, 2022 - ACS Publications
Lanthanide-based luminescent materials have unique properties and are well-studied for
many potential applications. In particular, the characteristic 5d→ 4f emission of divalent …

Lanthanide‐Based Molecular Cluster‐Aggregates: Optical Barcoding and White‐Light Emission with Nanosized {Ln20} Compounds

DA Gálico, AA Kitos, JS Ovens, FA Sigoli… - Angewandte …, 2021 - Wiley Online Library
Counterfeit goods represent a major problem to companies, governments, and customers,
affecting the global economy. In order to protect the authenticity of products and documents …

Toward Magneto‐Optical Cryogenic Thermometers with High Sensitivity: A Magnetic Circular Dichroism Based Thermometric Approach

DA Gálico, M Murugesu - Angewandte Chemie, 2023 - Wiley Online Library
Remote temperature probing at the cryogenic range is of utmost importance for the
advancement of future quantum technologies. Despite the notable achievements in …

High-performance luminescence thermometer with field-induced slow magnetic relaxation based on a heterometallic cyanido-bridged 3d–4f complex

V Tangoulis, V Nastopoulos, N Panagiotou… - Inorganic …, 2022 - ACS Publications
The 1: 1: 1 reaction of DyCl3· 6H2O, K3 [Co (CN) 6] and bpyO2 in H2O has provided access
to a complex with formula [DyCo (CN) 6 (bpyO2) 2 (H2O) 3]· 4H2O (1) in a very good yield …

A Multifunctional Dysprosium‐Carboxylato 2D Metall–Organic Framework

J González, P Sevilla, G Gabarró‐Riera… - Angewandte Chemie …, 2021 - Wiley Online Library
We report the microwave assisted synthesis of a bidimensional (2D) MOF of formula [Dy
(MeCOO)(PhCOO) 2] n (1) and its magnetically diluted analogue [La0. 9Dy0. 1 …

Inside-out/outside-in tunability in nanosized lanthanide-based molecular cluster-aggregates: modulating the luminescence thermometry performance via composition …

DA Galico, M Murugesu - ACS Applied Materials & Interfaces, 2021 - ACS Publications
Modulating the optical property of a material via structural modification is a powerful tool for
obtaining the desired optical output. If a material can be tuned inside (core) and outside …

Multifunctional DyIII Enantiomeric Pairs Showing Enhanced Photoluminescences and Third-Harmonic Generation Responses through the Coordination Role of Homochiral …

M Cui, L Yang, F Li, L Zhou, Y Song, SM Fang… - Inorganic …, 2021 - ACS Publications
By utilizing Dy (hfac) 3 (H2O) 2 to react with enantiomerically pure tridentate N, N, N-pincer
ligands, namely (−)/(+)-2, 6-bis (4′, 5′-pinene-2′-pyridyl) pyridine (LR and LS) …

Synthesis, luminescent and thermometric properties of the Tb3+ doped Gd2TeO6 phosphor

KD Ferreira, LA de Queiroz, JF Carvalho… - Journal of Alloys and …, 2024 - Elsevier
Abstract Gadolinium tellurate phosphor Gd 2 TeO 6 pure and Tb 3+ doped were successfully
synthesised by solid-state reaction. The crystal structure and photoluminescence properties …