Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes

K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

Strategies towards single molecule magnets based on lanthanide ions

R Sessoli, AK Powell - Coordination Chemistry Reviews, 2009 - Elsevier
We review here the synthetic strategies employed in a concerted effort to obtain new single
molecule magnets based on lanthanide ions in the framework of the research program on …

Single-molecule magnet engineering: building-block approaches

KS Pedersen, J Bendix, R Clérac - Chemical Communications, 2014 - pubs.rsc.org
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

Metal–organic derivatives with fluorinated ligands as precursors for inorganic nanomaterials

S Mishra, S Daniele - Chemical Reviews, 2015 - ACS Publications
Inorganic nanomaterials cover a wide range of applications in electronics, optics,
magnetism, catalysis, biomedical, and environmental issues. 1− 3 The properties of these …

The evolution of β-diketone or β-diketophenol ligands and related complexes

PA Vigato, V Peruzzo, S Tamburini - Coordination Chemistry Reviews, 2009 - Elsevier
The design and properties of the most relevant and illustrative examples of β-diketones or β-
ketophenols and related complexes, together with their evolution into more sophisticated …

Oximate-bridged trinuclear Dy− Cu− Dy complex behaving as a single-molecule magnet and its mechanistic investigation

F Mori, T Nyui, T Ishida, T Nogami… - Journal of the …, 2006 - ACS Publications
Lanthanide ions are supposed to be promising candidates for the elements of single-
molecule magnets (SMMs) because of the large magnetic momentum and anisotropy. We …

Heterometallic [Mn5‐Ln4] Single‐Molecule Magnets with High Anisotropy Barriers

V Mereacre, AM Ako, R Clérac… - … A European Journal, 2008 - Wiley Online Library
The reaction of [Mn6O2 (Piv) 10 (4‐Me‐py) 2.5 (PivH) 1.5](1)(py: pyridine, Piv: pivilate) with
N‐methyldiethanolamine (mdeaH2) and Ln (NO3) 3⋅ 6 H2O in MeCN leads to a series of …

Effects of 3d–4f Magnetic Exchange Interactions on the Dynamics of the Magnetization of DyIII‐MII‐DyIII Trinuclear Clusters

F Pointillart, K Bernot, R Sessoli… - Chemistry–A European …, 2007 - Wiley Online Library
Abstract [{Dy (hfac) 3} 2 {Fe (bpca) 2}]⋅ CHCl3 ([Dy2Fe]) and [{Dy (hfac) 3} 2 {Ni (bpca) 2}]⋅
CHCl3 ([Dy2Ni])(in which hfac−= 1, 1, 1, 5, 5, 5‐hexafluoroacetylacetonate and bpca−= bis …

Defect-Dicubane Ni2Ln2 (Ln = Dy, Tb) Single Molecule Magnets

KC Mondal, GE Kostakis, Y Lan… - Inorganic …, 2011 - ACS Publications
Two pairs of Ni2Dy2 and Ni2Tb2 complexes,[Ni2Ln2 (L) 4 (NO3) 2 (DMF) 2]{Ln= Dy (1), Tb
(2)} and [Ni2Ln2 (L) 4 (NO3) 2 (MeOH) 2]· 3MeOH {Ln= Dy (3), Tb (4)}(H2L is the Schiff base …

Cluster-based single-molecule magnets

CJ Milios, REP Winpenny - Molecular Nanomagnets and Related …, 2015 - Springer
This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …