Chiral sulfones, especially those compounds whose sulfone groups are directly connected
to the chiral centers, are privileged building blocks in many natural products and bioactive …

This research explores the enantioselective hydrosulfonylation of various α, β‐unsaturated
carbonyl compounds via the use of visible light and redox‐active chiral Ni‐catalysis …

A carbene-catalyzed sulfonylation reaction between enone aryl aldehydes and sulfonyl
chlorides is disclosed. The reaction effectively installs sulfone moieties in a highly …

Developing a general method that leads to the formation of different classes of chiral
bioactive compounds and their stereoisomers is an attractive but challenging research topic …

This review summarizes current developments, novel synthetic routes for Ruthenium
tethered chiral catalyst, and its derivatives along with its application in asymmetric synthesis …

Four-membered carbocycles are fundamental substructures in bioactive molecules and
approved drugs and serve as irreplaceable building blocks in organic synthesis. However …

Developing innovative dynamic kinetic resolution (DKR) modes and achieving the highly
regio-and enantioselective semihydrogenation of unsymmetrical α-diketones are two …

A catalytic protocol for the enantio-and diastereoselective reduction of α-substituted-β-keto
carbonitriles is described. The reaction involves a DKR-ATH process with the simultaneous …

The asymmetric hydrogenation (AH) of N-unprotected indoles is a straightforward, yet
challenging method to access biologically interesting NH chiral indolines. This method has …

Against the backdrop of the well-known O-sulfonylation of cyclopropyl alcohols with sulfonyl
chlorides, we examined the feasibility of conducting regioselective C-sulfonylation. By …