This review is the first to collate and summarize main data on named and unnamed
rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides …

This review focuses on the intramolecular cyclization of molecules through C–O, C–N and C–
S bonds forming C–H functionalizations with an emphasis on the literature after 2000 …

A facile method for the synthesis of challenging medium-sized cyclic ethers has been
developed via a novel oxidative rearrangement of benzylic tertiary alcohols. The reaction …

Oxepane motifs are prevalent in both naturally and synthetically bioactive molecules. We
report herein a photoredox-catalyzed formal [5+ 2] annulation of N-alkoxypyridiniums and 1 …

We report a general synthetic entry to dihydrooxepine-spiroisoxazoline (DOSI) natural
products that culminated in the first racemic total synthesis of psammaplysin A. For the …

The iodine-catalyzed catalytic formal [3+ 3+ 1] cycloaddition for the preparation of a seven-
membered O-heterocyclic ring is presented, which is an achievement of methyl and carbonyl …

The Cope rearrangement of 2, 3-divinyloxiranes, a rare example of epoxide C–C bond
cleavage, results in 4, 5-dihydrooxepines which are amenable to hydrolysis, furnishing 1, 6 …

The copper-catalyzed selective mono-N-alkylation of primary amides with bis (trialkylsilyl)
peroxides as alkylating agents was reported. The results of a mechanistic study suggest that …

This minireview focuses on recent advances in the synthesis of seven‐membered ring
oxacycles, whether saturated, unsaturated, fused or isolated. We cover a remarkable variety …

A simple, efficient, and regioselective synthesis of 3-methyl-3, 4-dihydrocoumarins is
reported. The reaction of 2-allyl phenols with synthesis gas was catalyzed by PdI2, and 1, 3 …