Switchable cobalt coordination polymers: Spin crossover and valence tautomerism

O Drath, C Boskovic - Coordination Chemistry Reviews, 2018 - Elsevier
Electronically labile, or switchable, cobalt coordination polymers exhibit reversible spin
crossover (SCO) or valence tautomeric (VT) transitions upon the application of an external …

Guest‐Dependent Spin‐Transition Behavior of Porous Coordination Polymers

R Ohtani, S Hayami - Chemistry–A European Journal, 2017 - Wiley Online Library
The host–guest composites of Hofmann‐type iron (II) spin‐transition (ST) porous
coordination polymers incorporating guest molecules show guest‐dependent ST behavior in …

Anion effects on spin crossover systems: from supramolecular chemistry to magnetism

SZ Zhao, HW Zhou, CY Qin, HZ Zhang… - … A European Journal, 2023 - Wiley Online Library
The field of anion supramolecular chemistry has received more and more attention in recent
years. Anions with diverse types and geometries have been widely used for the synthesis of …

Incorporation of switchable inorganic building blocks into heterometallic coordination polymers

MG Robb, S Brooker - Crystal Growth & Design, 2023 - ACS Publications
A new terpyridine-based ligand with a pyridyl-1, 2, 4-triazoyl bidentate pocket “out the back”
has been used to synthesize monometallic CoII, FeII, and RuII complexes where the …

Reversible Spin-State Switching and Tuning of Nuclearity and Dimensionality via Nonlinear Pseudohalides in Cobalt (II) Complexes

S Ghosh, S Kamilya, M Rouzières, R Herchel… - Inorganic …, 2020 - ACS Publications
The self-assembly of a macrocyclic tetradentate ligand, cobalt (II) tetrafluoroborate, and
nonlinear pseudohalides (dicyanamide and tricyanomethanide) has led to two cobalt (II) …

Reversible thermo-induced spin crossover in a mononuclear cis-dicyanamido-cobalt (ii) complex containing a macrocyclic tetradentate ligand

S Ghosh, S Selvamani, S Mehta, A Mondal - Dalton Transactions, 2020 - pubs.rsc.org
We present a unique investigation of a mononuclear cis-dicyanamido-cobalt (II) complex,[Co
(L)(N (CN) 2) 2](1)(L= N, N′-di-tert-butyl-2, 11-diaza [3, 3](2, 6) pyridinophane), which …

Non-traditional thermal behavior of Co (II) coordination networks showing slow magnetic relaxation

A Świtlicka, B Machura, A Bieńko, S Kozieł… - Inorganic Chemistry …, 2021 - pubs.rsc.org
Three new coordination polymers, one-dimensional ones [Co (5, 6-(Me) 2-bzim) 2 (dca)
2](1) and [Co (5-Mebzim) 2 (dca) 2] n (2) and two-dimensional polymer [Co (2-Mebzim)(dca) …

[HTML][HTML] Polynuclear Fe (II) complexes: Di/trinuclear molecules and coordination networks

JRG Mascarós, G Aromí, M Darawsheh - Comptes Rendus Chimie, 2018 - Elsevier
We review here the recent progress made in the synthesis of spin crossover (SCO) Fe (II)
coordination complexes with two or three metal atoms, as well as coordination polymers …

Tuning of spin crossover properties in a series of mononuclear cobalt (ii) complexes based on a macrocyclic tetradentate ligand and pseudohalide coligands

S Ghosh, S Selvamani, S Kamilya, S Mehta… - Dalton …, 2022 - pubs.rsc.org
The three mononuclear cobalt (II) complexes,[Co (L)(NCX) 2](L= N, N '-di-tert-butyl-2, 11-
diaza [3, 3](2, 6) pyridinophane, and X= S (1), Se (2), and [C (CN) 2](3)), have been …

Synthesis, crystal structures and magnetism of CuIILnIII N2O4-donor coordination compounds involving dicyanamides

SL Zhang, XF Fan, RL Du, BW Shen, XD Song, XQ Wei… - Polyhedron, 2021 - Elsevier
By the reaction of H 2 valen, Cu (NO 3) 2· 3H 2 O, LnCl 3· 6H 2 O and NaN (CN) 2, three
new heterometallic Cu II–Ln III complexes,[(Cu (valen) La (NO 3)(CH 3 OH)(dca)(μ-dca)] 2 …