Recent advances of stable Blatter radicals: synthesis, properties and applications

Y Ji, L Long, Y Zheng - Materials Chemistry Frontiers, 2020 - pubs.rsc.org
Radicals, organic molecules with unpaired electrons, are applied across different scientific
disciplines such as electronics, energy storage and biochemistry. Among them, due to the …

Recent advances in the chemistry of benzo [e][1, 2, 4] triazinyl radicals

FJM Rogers, PL Norcott, ML Coote - Organic & Biomolecular …, 2020 - pubs.rsc.org
Benzo [e][1, 2, 4] triazinyl, or Blatter radicals, are stable free radicals, first reported by Blatter
in 1968. In contrast to their nitroxide counterparts, their properties can be modified more …

Blatter radicals as bipolar materials for symmetrical redox-flow batteries

JS Steen, JL Nuismer, V Eiva… - Journal of the …, 2022 - ACS Publications
Redox-active organic molecules are promising charge-storage materials for redox-flow
batteries (RFBs), but material crossover between the posolyte and negolyte and chemical …

Thermally and magnetically robust triplet ground state diradical

N Gallagher, H Zhang, T Junghoefer… - Journal of the …, 2019 - ACS Publications
High spin (S= 1) organic diradicals may offer enhanced properties with respect to several
emerging technologies, but typically exhibit low singlet triplet energy gaps and possess …

High-spin organic diradical with robust stability

NM Gallagher, JJ Bauer, M Pink, S Rajca… - Journal of the …, 2016 - ACS Publications
Triplet ground-state organic molecules are interesting with respect to several emerging
technologies but typically exhibit limited stability. We report two organic diradicals, one of …

High-power-density organic radical batteries

C Friebe, US Schubert - Electrochemical Energy Storage: Next Generation …, 2019 - Springer
Batteries that are based on organic radical compounds possess superior charging times and
discharging power capability in comparison to established electrochemical energy-storage …

Methyl-driven overhauser dynamic nuclear polarization

FA Perras, DF Flesariu, SA Southern… - The Journal of …, 2022 - ACS Publications
The Overhauser effect is unique among DNP mechanisms in that it requires the modulation
of the electron–nuclear hyperfine interactions. While it dominates DNP in liquids and metals …

The environment-dependent behavior of the Blatter radical at the metal–molecule interface

JZ Low, G Kladnik, LL Patera, S Sokolov, G Lovat… - Nano Letters, 2019 - ACS Publications
Stable organic radicals have potential applications for building organic spintronic devices.
To fulfill this potential, the interface between organic radicals and metal electrodes must be …

[HTML][HTML] Asymmetric and zwitterionic Blatter diradicals

F Miao, Y Ji, B Han, SM Quintero, H Chen, G Xue… - Chemical …, 2023 - pubs.rsc.org
Asymmetric diradical molecular systems with different resonance mechanisms are largely
unexplored. Herein, two conjugated asymmetric diradicals with Blatter and phenoxyl …

[HTML][HTML] Blatter radical as a polymeric active material in organic batteries

A Saal, C Friebe, US Schubert - Journal of Power Sources, 2022 - Elsevier
The Blatter radical is applied in a cross-linked polymer to yield a stable and quickly
chargeable electrode material for organic radical batteries. Different electrolytes are …