Synthetic iron–sulfur clusters of general formulation [Fe m S q L l] z with core atoms Fe and S
and terminal ligands L constitute a family of molecular clusters with remarkably diverse …

We report an alkoxy radical process for the C–C bond cleavage and functionalization of
unstrained tertiary and secondary cyclic alcohols. In the absence of a chlorine atom, the …

Various valuable properties of azoarenes (“azo dyes”), including their vivid colors and their
facile cis–trans photoisomerization, lead to their wide use in the chemical industry. As a …

Iron compounds containing a bridging oxo or sulfido moiety are ubiquitous in biological
systems, but substitution with the heavier chalcogenides selenium and tellurium, however, is …

1, 2-cis-Furanosides are present in various biomedically relevant glycosides, and their
stereoselective synthesis remains a significant challenge. In this vein, we have developed a …

Four-membered ring structure is important in organic chemistry, and selective cleavage and
functionalization of these strained rings are of great interest. However, direct α …

Template‐assisted synthesis of well‐defined polynuclear clusters remains a challenge for
[M4] square planar topologies. Herein, we present a tetraamine scaffold RL (NH2) 4, where …

Coordination of the tridentate ligand bis (2-diphenylphosphinoethyl) phenylphosphine (P3)
to cobalt forms [(CH3CN) 2CoIIP3](BF4) 2 (Co II P 3). In the presence of the Brönsted base …

Herein we report the synthesis of Cr imido complexes in bis (alkoxide) ligand environments
and their nitrene transfer reactivity with isocyanides. The reaction of Cr2 (OR) 4 (OR= OC t …

High-valent cobalt carbene Co (OR) 2 (═ CPh2)(OR= OC t Bu2Ph) undergoes reaction with
various isocyanides CNR′(CNR′= 2, 6-dimethylphenyl isocyanide, 4-methoxyphenyl …