Recent progress in transition metal complexes supported by multidentate ligands featuring group 13 and 14 elements as coordinating atoms

T Komuro, Y Nakajima, J Takaya… - Coordination Chemistry …, 2022 - Elsevier
Over the past decade, significant progress has been made in the chemistry of transition
metal complexes supported by multidentate chelate ligands, such as pincer-type ligands, in …

Tunable σ-accepting, Z-type ligands for organometallic catalysis

D You, FP Gabbaï - Trends in Chemistry, 2019 - cell.com
Over the past decade, the chemistry of σ-accepting or Z-type ligands based on main group
elements has drawn renewed attention because of the realization that their interaction with a …

Tuning nickel with Lewis acidic group 13 metalloligands for catalytic olefin hydrogenation

RC Cammarota, CC Lu - Journal of the American Chemical …, 2015 - ACS Publications
A series of bimetallic complexes pairing zero-valent nickel with group 13 M (III) ions is
reported. Stronger Ni→ M (III) dative bonds that render Ni more electron-deficient are seen …

σ-Acceptor, Z-type ligands for transition metals

A Amgoune, D Bourissou - Chemical Communications, 2011 - pubs.rsc.org
The ability of Lewis acids to coordinate to transition metals as σ-acceptor ligands was
recognized as early as in the 1970's, but so-called Z-type ligands remained curiosities until …

Synthesis, structure, and catalysis of palladium complexes bearing a group 13 metalloligand: remarkable effect of an aluminum-metalloligand in hydrosilylation of CO2

J Takaya, N Iwasawa - Journal of the American Chemical Society, 2017 - ACS Publications
Efficient synthesis and catalysis of a series of palladium complexes having a group 13
metalloligand (Al, Ga, In) are reported utilizing 6, 6 ″-bis (phosphino) terpyridine as a new …

[图书][B] Ligand Design in Metal Chemistry

M Stradiotto, RJ Lundgren - 2016 - Wiley Online Library
Names: Stradiotto, Mark, author.| Lundgren, Rylan, author. Title: Ligand design in metal
chemistry: reactivity and catalysis/[edited by] Mark Stradiotto, Rylan Lundgren. Description …

Metal–alane adducts with zero-valent nickel, cobalt, and iron

PA Rudd, S Liu, L Gagliardi… - Journal of the American …, 2011 - ACS Publications
Coordination complexes that pair a zero-valent transition metal (Ni, Co, Fe) and an
aluminum (III) center have been prepared. They add to the few examples of structurally …

[图书][B] Frustrated Lewis Pairs

G Erker, DW Stephan - 2013 - Springer
Up until recently, our understanding of the chemistry resulting from the combination of Lewis
acids and bases had not evolved much since Lewis' time. In large part, the formation of …

A tris (triphenylphosphine) aluminum ambiphilic precatalyst for the reduction of carbon dioxide with catecholborane

MA Courtemanche, J Larouche, MA Legare, W Bi… - …, 2013 - ACS Publications
The ambiphilic species Al (C6H4 (o-PPh2)) 3 (2) was synthesized and fully characterized,
notably using X-ray diffraction. Species 2 exhibits pseudo-bipyramidal-trigonal geometry …

Lewis Acid-Assisted C(sp3)–C(sp3) Reductive Elimination at Gold

CA Theulier, Y García-Rodeja, K Miqueu… - Journal of the …, 2023 - ACS Publications
The phosphine-borane i Pr2P (o-C6H4) BFxyl2 (Fxyl= 3, 5-(F3C) 2C6H3) 1-Fxyl was found
to promote the reductive elimination of ethane from [AuMe2 (μ-Cl)] 2. Nuclear magnetic …