Over the past decade, the chemistry of σ-accepting or Z-type ligands based on main group elements has drawn renewed attention because of the realization that their interaction with a …
RC Cammarota, CC Lu - Journal of the American Chemical …, 2015 - ACS Publications
A series of bimetallic complexes pairing zero-valent nickel with group 13 M (III) ions is reported. Stronger Ni→ M (III) dative bonds that render Ni more electron-deficient are seen …
The ability of Lewis acids to coordinate to transition metals as σ-acceptor ligands was recognized as early as in the 1970's, but so-called Z-type ligands remained curiosities until …
J Takaya, N Iwasawa - Journal of the American Chemical Society, 2017 - ACS Publications
Efficient synthesis and catalysis of a series of palladium complexes having a group 13 metalloligand (Al, Ga, In) are reported utilizing 6, 6 ″-bis (phosphino) terpyridine as a new …
PA Rudd, S Liu, L Gagliardi… - Journal of the American …, 2011 - ACS Publications
Coordination complexes that pair a zero-valent transition metal (Ni, Co, Fe) and an aluminum (III) center have been prepared. They add to the few examples of structurally …
Up until recently, our understanding of the chemistry resulting from the combination of Lewis acids and bases had not evolved much since Lewis' time. In large part, the formation of …
The ambiphilic species Al (C6H4 (o-PPh2)) 3 (2) was synthesized and fully characterized, notably using X-ray diffraction. Species 2 exhibits pseudo-bipyramidal-trigonal geometry …
The phosphine-borane i Pr2P (o-C6H4) BFxyl2 (Fxyl= 3, 5-(F3C) 2C6H3) 1-Fxyl was found to promote the reductive elimination of ethane from [AuMe2 (μ-Cl)] 2. Nuclear magnetic …