Recent advances in the use of dimethyl sulfoxide as a synthon in organic chemistry

H Lu, Z Tong, L Peng, Z Wang, SF Yin… - Topics in Current …, 2022 - Springer
Dimethyl sulfoxide (DMSO), as extremely important aprotic polar solvent and reaction
medium, has attracted widespread attention from chemists in recent years due to its wide …

Nucleophilic neutralization of organophosphates: lack of selectivity or plenty of versatility?

VB Silva, RB Campos, P Pavez… - The Chemical …, 2021 - Wiley Online Library
Neutralization of organophosphates is an issue of public health and safety, involving
agrochemicals and chemical warfare. A promising approach is the nucleophilic …

[HTML][HTML] Ultrasound and microwave assisted-synthesis of ZIF-8 from zinc oxide for the adsorption of phosphate

L Bazzi, I Ayouch, H Tachallait, SEL Hankari - Results in Engineering, 2022 - Elsevier
The conversion of solid matters into metal-organic frameworks has emerged as a new
alternative for the synthesis of MOFs. Various synthesis methods have been applied for this …

Imidazole-derived graphene nanocatalysts for organophosphate destruction: Powder and thin film heterogeneous reactions

L Hostert, SF Blaskievicz, JES Fonsaca… - Journal of …, 2017 - Elsevier
Promoting efficient organophoshate (OP) destruction has been of increasing interest, mainly
due to their highly toxic nature and broad use as agrochemicals and chemical warfare. It is …

Dopant-free dipole-type hole transport materials with alkali cation for enhanced stability in perovskite solar cells

H Kim, M Hashimoto, Y Ohkura, T Ito… - Chemical Engineering …, 2025 - Elsevier
The development of dopant-free hole transport layers (HTL) aimed at modifying the spiro-
OMeTAD (spiro) structure has been extensively explored to enhance the long-term stability …

Phosphate Triester Hydrolysis by Mononuclear Iron (III) Complexes: the Role of Benzimidazole in the Second Coordination Sphere

E Luiz, G Farias, M Alzamora… - European Journal of …, 2024 - Wiley Online Library
Over the years, phosphate ester hydrolysis catalyzed by coordination compounds has
attracted extensive research on developing new bioinspired compounds. However, the …

Post-modified polymer with imidazole groups as an efficient and reusable heterogeneous catalyst for organophosphate degradation

EC Leopoldino, G Pinheiro, RJ Alves, A Gerola… - Materials Today …, 2021 - Elsevier
In this work, the commercial polymer poly (ethylene-alt-maleic anhydride) was used as a
platform for the preparation of an imidazole-rich polymeric catalyst (PEIIm) designed for …

Degradation of organophosphates promoted by 1, 2, 4-triazole anion: exploring scaffolds for efficient catalytic systems

JM Fernandes, RN Soek… - The Journal of …, 2021 - ACS Publications
Organophosphate (OP) pesticides are responsible for numerous human deaths every year.
Nucleophilic substitution is an important method to mitigate the toxicity of obsolete stocks of …

The importance of methyl positioning and tautomeric equilibria for imidazole nucleophilicity

RB Campos, LRA Menezes, A Barison… - … A European Journal, 2016 - Wiley Online Library
Imidazole (IMZ) rings catalyze many biological dephosphorylation processes. The methyl
positioning effect on IMZs reactivity has long intrigued scientists and its full understanding …

Solvent and solvation effects on reactivities and mechanisms of phospho group transfers from phosphate and phosphinate esters to nucleophiles

I Onyido, OF Obumselu, CI Egwuatu… - Frontiers in Chemistry, 2023 - frontiersin.org
Organophosphorus esters fulfil many industrial, agricultural, and household roles. Nature
has deployed phosphates and their related anhydrides as energy carriers and reservoirs, as …