Transition metal–sulfur (M–S) compounds are an indispensable means for biological
systems to convert N2 into NH3 (biological N2 fixation), and these may have emerged by …

Abstract The {Mn 4 O 5 Ca} cluster of photosystem II is a well-known cubane-like transition-
metal (TM) cluster that plays important roles in solar energy conversion. The artificial …

Data on the electronic structure and redox, magnetic, luminescent, nonlinear optical and
catalytic properties of tri-and tetranuclear molybdenum and tungsten chalcogenide clusters …

The state-of-the-art and prospects of the development of chemistry of chalcogenide clusters
of Group 5–7 metals of the Periodic Table are discussed. The main structural types, methods …

Cluster excision of polymeric {Mo3S7Cl4} n phases with chiral phosphane (+)‐1, 2‐bis [(2R,
5R)‐2, 5‐(dimethylphospholan‐1‐yl)] ethane ((R, R)‐Me‐BPE) or with its enantiomer ((S, S) …

Treatment of the cationic incomplete cubane-type sulfido complex [(Cp* Mo) 3 (μ2-S) 3 (μ3-
S)][PF6](2; Cp*= η5-C5Me5) with [Ni (cod) 2](cod= 1, 5-cyclooctadiene) afforded the …

The present article reviews synthetic approaches to efficiently prepare Mo3S7 clusters
coordinated to 1, 2-bis-dithiolene ligands of general formula [Mo3S7 (dithiolene) 3] 2 …

The use of the [Mo3S4 (Hnta) 3] 2− complex (nta3−= nitrilotriacetate) as structuring agent
toward the self-condensation process of the [Mo2O2S2 (OH2) 6] 2+ cation leads to the …

The synthesis, molecular and crystal structures and chemical transformations of homometal
chalcogenide clusters of vanadium, niobium and tantalum are considered. These metals …

Triangular [Mo3S4] clusters are known to serve as platforms to accommodate a metal atom
M, furnishing cubic [Mo3S4M] clusters. In this study, three [Mo3S4] clusters supported by η5 …