Towards the development of the emerging process of CO 2 heterogenous hydrogenation into high-value unsaturated heavy hydrocarbons

J Wei, R Yao, Y Han, Q Ge, J Sun - Chemical Society Reviews, 2021 - pubs.rsc.org
The emerging process of CO2 hydrogenation through heterogenous catalysis into important
bulk chemicals provides an alternative strategy for sustainable and low-cost production of …

Molecular views on mechanisms of Brønsted acid-catalyzed reactions in zeolites

C Chizallet, C Bouchy, K Larmier… - Chemical …, 2023 - ACS Publications
The Brønsted acidity of proton-exchanged zeolites has historically led to the most impactful
applications of these materials in heterogeneous catalysis, mainly in the fields of …

Asymmetric pore windows in MOF membranes for natural gas valorization

S Zhou, O Shekhah, A Ramírez, P Lyu, E Abou-Hamad… - Nature, 2022 - nature.com
To use natural gas as a feedstock alternative to coal and oil, its main constituent, methane,
needs to be isolated with high purity. In particular, nitrogen dilutes the heating value of …

First-generation organic reaction intermediates in zeolite chemistry and catalysis

X Gong, M Caglayan, Y Ye, K Liu, J Gascon… - Chemical …, 2022 - ACS Publications
Zeolite chemistry and catalysis are expected to play a decisive role in the next decade (s) to
build a more decentralized renewable feedstock-dependent sustainable society owing to the …

Carbon deposit analysis in catalyst deactivation, regeneration, and rejuvenation

ETC Vogt, D Fu, BM Weckhuysen - … Chemie International Edition, 2023 - Wiley Online Library
Hydrocarbon conversion catalysts suffer from deactivation by deposition or formation of
carbon deposits. Carbon deposit formation is thermodynamically favored above 350° C …

Aromatics production via methanol-mediated transformation routes

T Li, T Shoinkhorova, J Gascon, J Ruiz-Martinez - ACS Catalysis, 2021 - ACS Publications
The methanol-to-aromatics (MTA) process is regarded as a promising route to produce
aromatic commodities through non-petroleum carbon resources, such as biomass, waste …

Recent progress in methanol‐to‐olefins (MTO) catalysts

M Yang, D Fan, Y Wei, P Tian, Z Liu - Advanced materials, 2019 - Wiley Online Library
Methanol conversion to olefins, as an important reaction in C1 chemistry, provides an
alternative platform for producing basic chemicals from nonpetroleum resources such as …

The Oxygenate-Mediated Conversion of COx to Hydrocarbons─On the Role of Zeolites in Tandem Catalysis

J Xie, U Olsbye - Chemical reviews, 2023 - ACS Publications
Decentralized chemical plants close to circular carbon sources will play an important role in
shaping the postfossil society. This scenario calls for carbon technologies which valorize …

Elucidation of radical-and oxygenate-driven paths in zeolite-catalysed conversion of methanol and methyl chloride to hydrocarbons

A Cesarini, S Mitchell, G Zichittella, M Agrachev… - Nature …, 2022 - nature.com
Understanding hydrocarbon generation in the zeolite-catalysed conversions of methanol
and methyl chloride requires advanced spectroscopic approaches to distinguish the …

Selectivity descriptors for the direct hydrogenation of CO2 to hydrocarbons during zeolite-mediated bifunctional catalysis

A Ramirez, X Gong, M Caglayan, SAF Nastase… - Nature …, 2021 - nature.com
Cascade processes are gaining momentum in heterogeneous catalysis. The combination of
several catalytic solids within one reactor has shown great promise for the one-step …