Pentadienyl complexes of the group 4 transition metals

L Stahl, RD Ernst - Advances in Organometallic Chemistry, 2007 - Elsevier
Publisher Summary This chapter focuses on the advances made in the pentadienyl
chemistry of three elements—namely, titanium, zirconium, and hafnium. As group 4 …

Facile ruthenium (IV)-catalyzed single and double allylation of indole compounds using alcohols as substrates: Aspects of ruthenium (IV) allyl chemistry

S Gruber, AB Zaitsev, M Wörle, PS Pregosin… - …, 2008 - ACS Publications
The dicationic Ru (IV) salt [Ru (Cp*)(η3-C3H5)(CH3CN) 2](PF6) 2 is shown to be an
excellent and rapid catalyst for the C-allylation of indole compounds using allyl alcohols as …

Synthetic Approaches to (smif)2Ti (smif = 1,3-di-(2-pyridyl)-2-azaallyl) Reveal Redox Non-Innocence and C–C Bond-Formation

BA Frazier, PT Wolczanski, I Keresztes… - Inorganic …, 2012 - ACS Publications
Attempted syntheses of (smif) 2Ti (smif= 1, 3-di-(2-pyridyl)-2-azaallyl) based on metatheses
of TiCl n L m (n= 2–4) with M (smif)(M= Li, Na), in the presence of a reducing agent (Na/Hg) …

Vanadium organometallics

C Lorber - Reference Module in Chemistry, Molecular Sciences …, 2015 - hal.science
This review surveys the organometallic chemistry of vanadium during the period 1993-2014.
It is an updated version of the" Vanadium" chapter in COMC-III (2007) that originally covered …

Synthesis and coordination of a ferrocenyl-substituted bicyclic phosphite

O Bárta, I Císařová, P Štěpnička - Journal of Organometallic Chemistry, 2015 - Elsevier
Abstract {[Tris (hydroxymethyl) methylamino] carbonyl} ferrocene (1) reacts with phosphorus
(III) chloride in the presence of pyridine or triethylamine to afford a ferrocenyl-substituted …

Synthesis, structure and hapticity interconversion reactions of pentahapto-bonded cyclooctadienyl complexes of molybdenum

DM Spencer, RL Beddoes, M Helliwell… - Dalton …, 2003 - pubs.rsc.org
The pentahapto-bonded cyclooctadienylmolybdenum complexes [Mo (CO) 2 (L2)(1–3: 5, 6-
η-C8H11)][BF4](L2= Ph2P (CH2) nPPh2, n= 1,(dppm), 1a; n= 2,(dppe), 2a) are synthesised …

11 Vanadium, niobium and tantalum

J Malito - Annual Reports Section" A"(Inorganic Chemistry), 2003 - pubs.rsc.org
[V (But 2pz) 2Cl (THF) 2] and [V (But 2pz) 3 (THF)] may be the first examples of η2-
pyrazolato co-ordination to ad 2 metal centre. The first tantalasilsesequioxanes have been …

Titanium: Organometallic Chemistry

EA Mintz - Encyclopedia of Inorganic and Bioinorganic …, 2011 - Wiley Online Library
The majority of titanium organometallic chemistry involves complexes in which the titanium
is in its highest oxidation state (+ 4) with cyclopentadienyl derivatives as ancillary ligands …

Synthesis and reactions of cycloheptadienyl and cyclooctadienyl tungsten complexes: X-ray crystal structure of [W (CO) 2 (PPh3) 2 (η5-C7H9)][BF4]

KP Carruthers, M Helliwell, JR Hinchliffe… - Journal of …, 2004 - Elsevier
Protonation of the cycloheptatriene complex [W (CO) 3 (η6-C7H8)] with H [BF4]· Et2O in
CH2Cl2 affords the cycloheptadienyl system [W (CO) 3 (η5-C7H9)][BF4](1). Complex 1 …

Vibrational spectra of some co-ordinated ligands

G Davidson - 2007 - books.rsc.org
Vibrational spectra of some co-ordinated ligands | Spectroscopic Properties of Inorganic and
Organometallic Compounds | Books Gateway | Royal Society of Chemistry Skip to Main …