Recent advances in crystalline hybrid photochromic materials driven by electron transfer

SD Han, JX Hu, GM Wang - Coordination Chemistry Reviews, 2022 - Elsevier
Photochromic materials have broad application prospects in the fields of molecular
switching, detection, biological, and molecular machines. Crystalline hybrid photochromic …

Second-order nonlinear optics in coordination chemistry: An open door towards multi-functional materials and molecular switches

PG Lacroix, I Malfant, C Lepetit - Coordination Chemistry Reviews, 2016 - Elsevier
Various inorganic and organometallic complexes exhibiting quadratic nonlinear optical
(NLO) properties (ie, linearly correlated to the square of the electric field E 2) are reviewed …

Nonlinear optical molecular switches as selective cation sensors

B Champagne, A Plaquet, JL Pozzo… - Journal of the …, 2012 - ACS Publications
This work demonstrates that the recognition of cations by molecular switches can give rise to
large contrasts of the second-order nonlinear optical (NLO) properties, which can therefore …

Quadruple photoresponsive functionality in a crystalline hybrid material: photochromism, photomodulated fluorescence, magnetism and nonlinear optical properties

SD Han, A Liu, Q Wei, JX Hu, J Pan… - … –A European Journal, 2021 - Wiley Online Library
As promising photoresponsive materials and potential smart materials, hybrid photochromic
materials (HPMs), especially for crystalline HPMs (CHPMs), have been broadly explored for …

Electron‐Transfer Photochromism To Switch Bulk Second‐Order Nonlinear Optical Properties with High Contrast

PX Li, MS Wang, MJ Zhang, CS Lin… - Angewandte Chemie …, 2014 - Wiley Online Library
The first bulk electron‐transfer photochromic compound with intrinsic second‐order
nonlinear optical (NLO) photoswitching properties has been synthesized. This system …

Second-order nonlinear optical switching with a record-high contrast for a photochromic and thermochromic bistable crystal

XS Xing, RJ Sa, PX Li, NN Zhang, ZY Zhou, BW Liu… - Chemical …, 2017 - pubs.rsc.org
Nonlinear optical (NLO) switchable materials are important for photonic and optoelectronic
technologies. One important issue for NLO photoswitching, the most studied physical …

NH2-MIL-53(Al): A High-Contrast Reversible Solid-State Nonlinear Optical Switch

P Serra-Crespo, MA Van Der Veen… - Journal of the …, 2012 - ACS Publications
The metal–organic framework NH2-MIL-53 (Al) is the first solid-state material displaying
nonlinear optical switching due to a conformational change upon breathing. A switching …

Solid-state reversible quadratic nonlinear optical molecular switch with an exceptionally large contrast.

Z Sun, J Luo, S Zhang, C Ji, L Zhou, S Li… - … (Deerfield Beach, Fla …, 2013 - europepmc.org
Exceptional nonlinear optical (NLO) switching behavior, including an extremely large
contrast (on/off) of∼ 35 and high NLO coefficients, is displayed by a solid-state reversible …

Two‐way molecular switches with large nonlinear optical contrast

F Mançois, JL Pozzo, J Pan, F Adamietz… - … A European Journal, 2009 - Wiley Online Library
Molecular switches: Highly efficient acido‐and photoswitchable frequency doublers (see
scheme) based on the indolinooxazolidine core are studied by means of hyper‐Rayleigh …

On the interface dipole at the pentacene− fullerene heterojunction: a Theoretical Study

M Linares, D Beljonne, J Cornil… - The Journal of …, 2010 - ACS Publications
The electronic structure at organic/organic interfaces plays a key role, among others, in
defining the quantum efficiency of organics-based photovoltaic cells. Here, we perform …