Fickian diffusion of radionuclides for engineered containment barriers: Diffusion coefficients, porosities, and complicating issues

CD Shackelford, SM Moore - Engineering Geology, 2013 - Elsevier
A review of the literature was undertaken primarily with the goal of discerning the types of
diffusion coefficients that have been reported with respect to diffusion of radionuclides …

Ionic transport in nano-porous clays with consideration of electrostatic effects

C Tournassat, CI Steefel - Reviews in Mineralogy and …, 2015 - pubs.geoscienceworld.org
The mineralogical and chemical properties of clays have been the subject of longstanding
study in the research community—in fact, entire journals are devoted to the topic. In the field …

Tracer diffusion in compacted, water-saturated bentonite

IC Bourg, G Sposito, ACM Bourg - Clays and Clay Minerals, 2006 - cambridge.org
Compacted Na-bentonite clay barriers, widely used in the isolation of solid-waste landfills
and other contaminated sites, have been proposed for a similar use in the disposal of high …

Carbon storage capacity of shale formations: Mineral control on CO2 adsorption

MP Murugesu, N Joewondo, M Prasad - International Journal of …, 2023 - Elsevier
When CO 2 is injected into storage reservoirs, buoyancy drives flow upward towards
overlying caprock layers that retard flow. Caprocks are commonly shale formations with …

Estimate of transport properties of porous media by microfocus X‐ray computed tomography and random walk simulation

Y Nakashima, Y Watanabe - Water Resources Research, 2002 - Wiley Online Library
The transport properties (porosity, surface‐to‐volume ratio of the pore space, diffusion
coefficient, and permeability) of a porous medium were calculated by image analysis and …

Self-diffusion of water and ions in clay barriers

IC Bourg, C Tournassat - Developments in Clay Science, 2015 - Elsevier
A well-known characteristic of clay-rocks and engineered bentonite barriers is their low
hydraulic permeability. In porous media with such low k values, at hydraulic pressure …

Diffusivity measurement of heavy ions in Wyoming montmorillonite gels by X-ray computed tomography

Y Nakashima - Journal of contaminant hydrology, 2003 - Elsevier
Medical X-ray computed tomography (CT) was applied to the measurement of the diffusion
coefficients of heavy ions in an artificial barrier material for the disposal of nuclear wastes …

Determination of diffusive transport in HDPy-montmorillonite by H2O-D2O exchange using in situ ATR-FTIR spectroscopy

B Schampera, S Dultz - Clay Minerals, 2009 - cambridge.org
The anion adsorption capability of clays can be improved significantly by modification with
certain organic cations. However, surface properties and the microstructure of the clay might …

Diffusive transport of water in porous fresh to altered mid-ocean ridge basalts

AV Simonyan, S Dultz, H Behrens - Chemical Geology, 2012 - Elsevier
Studying diffusive transport in porous rocks is of fundamental importance in understanding a
variety of geochemical processes including: element transfer, primary mineral dissolution …

Diffusion of H2O in smectite gels: Obstruction effects of bound H2O layers

Y Nakashima - Clays and Clay Minerals, 2003 - cambridge.org
In water-rich smectite gels, bound or less mobile H2O layers exist near negatively-charged
clay platelets. These bound H2O layers are obstacles to the diffusion of unbound H2O …