Arynes are among the most active organic intermediates and have found numerous
applications in expeditious preparation of substituted arenes. In the past 20 years, chemists …

Arynes and donor–acceptor (D–A) cyclopropanes are two classes of strained systems
having the potential for numerous applications in organic synthesis. The last two decades …

Sulfilimines are valuable compounds both in organic synthesis and in pharmaceuticals.
Here we developed a mild and simplified method for preparation of sulfilimines via selective …

This Feature Article is aimed at highlighting the recent developments in the transition-metal-
free molecular rearrangements involving arynes. The chemistry of arynes has shown …

Catalytic approaches to pharmaceutically important bioactive skeletons through gold
carbene intermediates have experienced a dramatic development in the last decade …

We herein report the unprecedented synthesis of diverse biologically important aza‐
heterocycles by employing sulfilimines as nitrene transfer reagents. This class of sulfur …

Inspired by the discovery of a S═ N bond in the collagen IV network and its essential role in
stabilizing basement membranes, sulfilimines have drawn much attention in the fields of …

In this work, a facile and efficient method for the synthesis of sulfilimines through
multicomponent reaction of arynes, sulfamides, and thiosulfonates was developed. A variety …

A three‐component thioamination reaction has been developed in the presence of
phenyliodonium (III) diacetate (PIDA) leading to the formation of a thioaminated products …

Sulfilimines, the aza analogues of sulfoxides, are of increasing interest in medicinal and
agrochemical research programs. However, the development of efficient routes for their …