Non-noble metal-based molecular complexes for CO2 reduction: From the ligand design perspective

DC Liu, DC Zhong, TB Lu - EnergyChem, 2020 - Elsevier
Molecular catalysts for electrochemical and photochemical CO 2 reduction have developed
rapidly during the past two decades. Using non-noble metal (Ni, Co, Mn, Fe, and Cu) …

Milestones and most recent advances in Corrole's Science and Technology

A Mahammed, Z Gross - Journal of the American Chemical …, 2023 - ACS Publications
The renaissance in corrole chemistry is strongly correlated with synthetic breakthroughs that
started in 1999, regarding the one-pot rather than multistep syntheses of this heme-like N4 …

Redox-Active Ligands in Electroassisted Catalytic H+ and CO2 Reductions: Benefits and Risks

N Queyriaux - ACS Catalysis, 2021 - ACS Publications
In the past decade, the use of redox-active ligands has emerged as a promising strategy to
improve catalyst selectivity, efficiency, and stability in electroassisted H+ and CO2 …

Corroles: the hitherto elusive parent macrocycle and its metal complexes

A Kumar, P Yadav, M Majdoub… - Angewandte Chemie …, 2021 - Wiley Online Library
Corroles, macrocycles that owe their name to the cobalt‐chelating prosthetic group of
vitamin B12 and share numerous features with the iron‐chelating porphyrin present in heme …

Copper Complexes of CF3-Substituted Corroles for Affecting Redox Potentials and Electrocatalysis

K Sudhakar, A Mahammed, QC Chen… - ACS Applied Energy …, 2020 - ACS Publications
Electrocatalysis by first-row transition metals chelated by porphyrins, corroles, and related
macrocycles gains increased attention due to the need of developing approaches for clean …

Cobalt-N4 macrocyclic complexes for heterogeneous electrocatalysis of the CO2 reduction reaction

Z Lin, Z Jiang, Y Yuan, H Li, H Wang, Y Tang… - Chinese Journal of …, 2022 - Elsevier
ABSTRACT Metal-N 4 (MN 4) macrocyclic complexes are interesting electrocatalysts due to
their well-defined structures and rich molecular tuning. Among them, metal phthalocyanines …

Recent advances in the rational designing of metalloporphyrinoid-based reduction catalysts: From molecular structural tuning to the application in catalysis

B Domingo-Tafalla, T Chatterjee… - Journal of Porphyrins …, 2023 - World Scientific
Electro and photochemical CO 2 reduction (CO 2 R) has emerged as a contemporary
research field for tackling the fossil fuel problems and construction of a modern chemical …

Heterogeneous electrocatalytic reduction of carbon dioxide with transition metal complexes

A Friedman, L Elbaz - Journal of Catalysis, 2021 - Elsevier
Reducing the atmospheric CO 2 level is of a great interest these days, as it is negatively
affecting our environment. Despite the large efforts invested in development of technologies …

Unexpected Effect of Intramolecular Phenolic Group on Electrocatalytic CO2 Reduction

K Guo, X Li, H Lei, W Zhang, R Cao - ChemCatChem, 2020 - Wiley Online Library
Iron porphyrin 1 with appending phenolic group was synthesized and examined as
electrocatalyst for the carbon dioxide reduction (CO2RR). Unexpectedly, the chloride salt 1 …

Hydrogen evolution activity of cobalt corroles

R Kubba, S Kumar, N Fridman, SG Warkar… - Inorganica Chimica …, 2024 - Elsevier
An electrochemical study of a series of bis-pyridine ligated A 2 B type cobalt corroles has
been carried out. The impact of substituting with electron withdrawing or donating groups on …