Supercritical fluids as solvents for chemical and materials processing

CA Eckert, BL Knutson, PG Debenedetti - Nature, 1996 - nature.com
Fluids near their critical point have dissolving power comparable to that of liquids, are much
more compressible than dilute gases, and have transport properties intermediate between …

Activation and reaction volumes in solution. 3

A Drljaca, CD Hubbard, R Van Eldik… - Chemical …, 1998 - pubmed.ncbi.nlm.nih.gov

Reactions at supercritical conditions: applications and fundamentals

PE Savage, S Gopalan, TI Mizan, CJ Martino… - AIChE …, 1995 - Wiley Online Library
Supercritical fluids posses properties that make them attractive as media for chemical
reactions. Conducting chemical reactions at supercritical conditions affords opportunities to …

[图书][B] Supercritical fluids: molecular interactions, physical properties, and new applications

T Sako - 2002 - books.google.com
New processing methods govern the progress in physical-chemical technology. The
potential of supercritical fluid methods is presented in a comprehensive way in this book. On …

[图书][B] Green solvents for chemistry: perspectives and practice

WM Nelson - 2003 - books.google.com
The aim of this book is to introduce the use of green solvents throughout chemistry and to
provide a comprehensive reference for solvents currently applicable in green chemistry. The …

Solute‐induced effects on the structure and thermodynamics of infinitely dilute mixtures

AA Chialvo, PT Cummings - AIChE journal, 1994 - Wiley Online Library
A general molecular‐based formalism developed rigorously establishes microscopic bases
of the supercritical solubility enhancement in terms of well‐defined molecular correlation …

Supercritical fluids in catalysis: opportunities of in situ spectroscopic studies and monitoring phase behavior

JD Grunwaldt, R Wandeler, A Baiker - Catalysis Reviews, 2003 - Taylor & Francis
A number of homogeneous and heterogeneous catalytic reactions have been successfully
performed in supercritical fluids (SCFs). An overview on recent developments in the areas of …

Vibrational spectroscopy in supercritical fluids: from analysis and hydrogen bonding to polymers and synthesis

M Poliakoff, SM Howdle… - … International Edition in …, 1995 - Wiley Online Library
Supercritical fluids are beginning to be used widely in chemistry. Applications range from
extraction and chromatography in analytical chemistry to solvents for reaction chemistry and …

Free-radical side-chain bromination of alkylaromatics in supercritical carbon dioxide

JM Tanko, JF Blackert - Science, 1994 - science.org
Free-radical side-chain brominations of alkylaromatics in supercritical carbon dioxide (SC-
CO2) are reported. Direct bromination of toluene and ethylbenzene form the corresponding …

Effect of local composition enhancements on the esterification of phthalic anhydride with methanol in supercritical carbon dioxide

JB Ellington, KM Park… - Industrial & engineering …, 1994 - ACS Publications
We report the pressure effect on the bimolecular rate constants for the esterification of
phthalic anhydride with methanol in supercritical carbon dioxide at 40 and 50 C. We observe …