Electrochemical dearomative spirocyclization

N Li, Z Shi, WZ Wang, Y Yuan… - Chemistry–An Asian …, 2023 - Wiley Online Library
Electrochemical dearomative spirocyclization serves as a green and sustainable approach
to convert the flat, two‐dimension aromatic feedstock into the value‐added three‐dimension …

Confronting the mysteries of oxidative reactive species in advanced oxidation processes: an elephant in the room

JH Wu, HQ Yu - Environmental Science & Technology, 2024 - ACS Publications
Advanced oxidation processes (AOPs) are rapidly evolving but still lack well-established
protocols for reliably identifying oxidative reactive species (ORSs). This Perspective …

Programmed alternating current optimization of Cu-catalyzed CH bond transformations

L Zeng, Q Yang, J Wang, X Wang, P Wang, S Wang… - Science, 2024 - science.org
Direct current (DC) electrosynthesis, which has undergone optimization over the past
century, plays a pivotal role in a variety of industrial processes. Alternating current (AC) …

Regiodivergent C− H Acylation of Arenes by Switching from Ionic‐to Radical‐Type Chemistry Using NHC Catalysis

J Reimler, XY Yu, N Spreckelmeyer… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract The Friedel–Crafts acylation reaction, which belongs to the class of electrophilic
aromatic substitutions is a highly valuable and versatile reaction in synthesis …

Visible-light-driven [3+ 2] cyclization of phenols with indoles and olefins using recyclable Ag 3 PO 4 nanoparticles

L Guo, G Chen, H Li, CH Tung, Y Wang - Green Chemistry, 2023 - pubs.rsc.org
Ag3PO4 promotes the oxidative [3+ 2] annulation of phenols with styrenes and indoles for
the syntheses of 2, 3-dihydrobenzofurans and benzofuroindolines under visible-light …

Electrochemical Skeletal Indole Editing via Nitrogen Atom Insertion by Sustainable Oxygen Reduction Reaction

BS Zhang, SL Homölle, T Bauch… - Angewandte Chemie …, 2024 - Wiley Online Library
Skeletal molecular editing gained considerable recent momentum and emerged as a
uniquely powerful tool for late‐stage diversifications. Thus far, superstoichiometric amounts …

[HTML][HTML] Molecularly Imprinted Polymer-based voltammetric sensor for amino acids/indazole derivatives synthetic cannabinoids detection

D Merli, E Lio, S Protti, R Coccia, A Profumo… - Analytica Chimica …, 2024 - Elsevier
Abstract Background Synthetic cannabinoids (SCs) are a broad class of illicit drugs that are
classified according to the chemical structure of the aromatic core that they present (ie …

Electrosynthesis of spiro-indolenines via dearomative arylation of indoles in batch and continuous flow

W Zhao, Y Lu, Y Qiao, X Yin, C Liu, Z Fang, J Zhu… - Organic …, 2023 - ACS Publications
An electrosynthesis of spiro-indolenines in batch and continuous flow was achieved through
dearomative arylation of indoles with good functional group compatibility. User-friendly …

Copper‐Catalyzed Oxygenative Skeletal Rearrangement of Tetrahydro‐β‐carbolines Using H2O and O2 as Oxygen Sources

YS Peng, W Wang, J Shi, W Wu… - Angewandte Chemie …, 2023 - Wiley Online Library
Herein, we report an unprecedented skeletal rearrangement reaction of tetrahydro‐β‐
carbolines enabled by copper‐catalyzed single‐electron oxidative oxygenation, in which …

Recent advances in electrocatalytic generation of indole-derived radical cations and their applications in organic synthesis

W Zhou, X Chen, L Lu, XR Song, MJ Luo… - Chinese Chemical …, 2024 - Elsevier
Indole-derived radical cations, open-shell reactive species, display distinctive dual reactivity
due to the carbon-centered radical and more electrophilic carbocation, which frequently …