Bis (2, 2, 2-trifluoroethyl) ethylphosphonate as novel high-efficient flame retardant additive for safer lithium-ion battery

X Zhu, X Jiang, X Ai, H Yang, Y Cao - Electrochimica Acta, 2015 - Elsevier
Abstract Bis (2, 2, 2-Trifluoroethyl) ethylphosphonate (TFEP) is first synthesized as a flame
retardant additive for conventional carbonate electrolyte to improve the safety of lithium ion …

Tris (2-(thiophen-2-yl) ethyl) phosphate to synergistically enhance electronic and ionic conductivities of cathode electrolyte interphase in high-voltage lithium ion …

X Liang, J Huang, Y Zheng, P Shi, Y Sun, H Xiang - Electrochimica Acta, 2019 - Elsevier
Abstract In this work, tris (2-(thiophen-2-yl) ethyl) phosphate is designed, synthesized and
applied as a functional electrolyte additive for lithium ion batteries with high-voltage LiCoO 2 …

Bis (fluoroalkyl) acrylic and methacrylic phosphate monomers, their polymers and some of their properties

CM Timperley, RE Arbon, M Bird, SA Brewer… - Journal of Fluorine …, 2003 - Elsevier
Ten fluoromonomers of structure (RFO) 2P (O) OCH2CH2OC (O) CR CH2 were made in
30–64% yield by treating the chloridates (RFO) 2P (O) Cl with HOCH2CH2OC (O) CR CH2 …

Fluorinated phosphorus compounds: Part 6. The synthesis of bis (fluoroalkyl) phosphites and bis (fluoroalkyl) phosphorohalidates

CM Timperley, RE Arbon, SA Saunders… - Journal of fluorine …, 2002 - Elsevier
Reaction of phosphorus trichloride with tert-butanol and fluoroalcohols gave bis (fluoroalkyl)
phosphites (RFO) 2P (O) H in 42–89% yield, where RF= HCF2CH2, H (CF2) 2CH2, H (CF2) …

Fluorinated phosphorus compounds: Part 4. A lack of anticholinesterase activity for four tris (fluoroalkyl) phosphates

CM Timperley, DJ Sellers, MJ Waters - Journal of Fluorine Chemistry, 2001 - Elsevier
Whilst examining the chemistry of a series of tris (fluoroalkyl) phosphates as potential fire
retardants, concern was raised over their possible anticholinesterase activity. Bimolecular …

Syntheses and properties of fluorinated phosphate acrylates used for UV-curing coatings

H Miao, Z Huang, L Cheng, W Shi - Progress in Organic Coatings, 2009 - Elsevier
The acrylated perfluoroalkyl phosphates (PFPA I and PFPA II) used as an oligomer and
monomer, respectively, for UV-curing systems were synthesized and characterized with 1H …

Fluorinated phosphorus compounds: Part 5. The boiling points of fluoroalkyl phosphoryl compounds

CM Timperley, MJ Waters - Journal of Fluorine Chemistry, 2001 - Elsevier
The relationship between structure and boiling point for several classes of phosphoryl
compounds having fluorinated or hydrocarbon ester groups is discussed, ie …

Reaction of polyfluoroalkyl dichlorophosphites with propargyl alcohol: synthesis and isomerization of polyfluoroalkyl di (2-propynyl) phosphites

NK Gusarova, SF Malysheva, NA Belogorlova… - Russian Chemical …, 2021 - Springer
Reaction of polyfluoroalkyl dichlorophosphites with propargyl alcohol: synthesis and isomerization
of polyfluoroalkyl di(2-propy Page 1 Russian Chemical Bulletin, International Edition, Vol. 70, No …

Phosphonyl compounds

CM Timperley - Best Synthetic Methods, 2015 - Elsevier
Synthetic methods for phosphonyl compounds are described. The methods cover 37 classes
of compounds. These include species of general structure: R (R'O) P (O) H, RP (O) X 2 [X …

General overview

CM Timperley, J Tattersall - Best Synthetic Methods, 2015 - Elsevier
The element phosphorus; principal compounds of phosphorus; phosphorus compounds in
living systems; a brief history of synthetic organophosphorus (OP) chemistry; nomenclature …