Transition Metal Complexes as Catalysts for the Electroconversion of CO2: An Organometallic Perspective

NW Kinzel, C Werlé, W Leitner - … Chemie International Edition, 2021 - Wiley Online Library
The electrocatalytic transformation of carbon dioxide has been a topic of interest in the field
of CO2 utilization for a long time. Recently, the area has seen increasing dynamics as an …

Secondary-Sphere Effects in Molecular Electrocatalytic CO2 Reduction

AW Nichols, CW Machan - Frontiers in chemistry, 2019 - frontiersin.org
The generation of fuels and value-added chemicals from carbon dioxide (CO2) using
electrocatalysis is a promising approach to the eventual large-scale utilization of intermittent …

A photoactivated Ir (iii) complex targets cancer stem cells and induces secretion of damage-associated molecular patterns in melanoma cells characteristic of …

G Vigueras, L Markova, V Novohradsky… - Inorganic Chemistry …, 2021 - pubs.rsc.org
Several anticancer chemotherapies, while eliminating the bulk of tumor cells, often fail, as
they do not obliterate a small fraction of malignant cancer stem cells (CSCs). Thus …

Unexpected Solvent Effect in Electrocatalytic CO2 to CO Conversion Revealed Using Asymmetric Metalloporphyrins

S Sinha, JJ Warren - Inorganic Chemistry, 2018 - ACS Publications
Rapid and efficient electrochemical CO2 reduction is an ongoing challenge for the
production of sustainable fuels and chemicals. In this work, electrochemical CO2 reduction …

Manganese and Rhenium Tricarbonyl Complexes Equipped with Proton Relays in the Electrochemical CO2 Reduction Reaction

J Mukherjee, I Siewert - European Journal of Inorganic …, 2020 - Wiley Online Library
The minireview focuses on the electrochemical CO2 reduction catalysed by manganese and
rhenium tricarbonyl complexes with α‐diimine ligands having pendant proton relays …

Synthesis, DNA binding, antibacterial and anticancer properties of two novel water-soluble copper (II) complexes containing gluconate

DH Cai, CL Zhang, QY Liu, L He, YJ Liu… - European Journal of …, 2021 - Elsevier
In this paper, two new Cu (II) complexes,[Cu (Gluc)(HPB)(H 2 O)] Gluc (CuG1) and [Cu
(Gluc)(HPBC)(H 2 O)] Gluc (CuG2)(where HPB= 2-(2′-pyridyl) benzimidazole, HPBC= 5 …

Examining the Importance of Hydrogen Bonding and Proton Transfer in Iron Porphyrin-Mediated Carbon Dioxide Upconversion

JJ Warren - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus The title should give a sense of the “big picture” of this Account, but what is it
really about? An unexpected change in research direction? A series of courageous and …

Dinuclear Rhenium Complex with a Proton Responsive Ligand as a Redox Catalyst for the Electrochemical CO2 Reduction

A Wilting, T Stolper, RA Mata, I Siewert - Inorganic Chemistry, 2017 - ACS Publications
Herein, we present the reduction chemistry of a dinuclear α-diimine rhenium complex,
1,[Re2 (L)(CO) 6Cl2], with a proton responsive ligand and its application as a catalyst in the …

Electrochemical Reduction of CO2 Catalyzed by Re(pyridine-oxazoline)(CO)3Cl Complexes

JK Nganga, CR Samanamu, JM Tanski… - Inorganic …, 2017 - ACS Publications
A series of rhenium tricarbonyl complexes coordinated by asymmetric diimine ligands
containing a pyridine moiety bound to an oxazoline ring were synthesized, structurally and …

Methane Generation from CO2 with a Molecular Rhenium Catalyst

JK Nganga, LM Wolf, K Mullick, E Reinheimer… - Inorganic …, 2021 - ACS Publications
The atomic-level tunability of molecular structures is a compelling reason to develop
homogeneous catalysts for challenging reactions such as the electrochemical reduction of …