A rational approach to organo‐photocatalysis: novel designs and structure‐property relationships

A Vega‐Peñaloza, J Mateos… - Angewandte Chemie …, 2021 - Wiley Online Library
Organic photocatalysts are emerging as viable and more sustainable tools than metal
complexes. Recently, the field of organo‐photocatalysis has experienced an explosion in …

Recent visible light and metal free strategies in [2+ 2] and [4+ 2] photocycloadditions

M Sicignano, RI Rodríguez… - European Journal of …, 2021 - Wiley Online Library
When aiming to synthesize molecules with elevated molecular complexity starting from
relatively simple starting materials, photochemical transformations represent an open …

Sulfur-Bridged Cationic Diazulenomethenes: Formation of Charge-Segregated Assembly with High Charge-Carrier Mobility

S Takahashi, M Murai, Y Hattori, S Seki… - Journal of the …, 2024 - ACS Publications
Sulfur-bridged cationic diazulenomethenes were synthesized and exhibited high stability
even under basic conditions due to the delocalization of positive charge over the whole π …

Characterization of a Lewis adduct in its inner and outer forms

WC Liu, FP Gabbaï - Science, 2024 - science.org
The entrance channel of bimolecular reactions sometimes involves the formation of outer
complexes as weakly bound, fleeting intermediates. Here, we characterize such an outer …

Visible light-mediated intermolecular crossed [2+ 2] cycloadditions using a MOF-supported copper triplet photosensitizer

J Guo, Q Xia, WY Tang, Z Li, X Wu, LJ Liu, WP To… - Nature Catalysis, 2024 - nature.com
Abstract The photochemical [2+ 2] cycloaddition of styrenes provides a frequently used route
for the synthesis of multi-substituted cyclobutanes. Despite the extensive studies in noble …

Stereoselective Synthesis of Cyclohepta[b]indoles by Visible‐Light‐Induced [2+2]‐Cycloaddition/retro‐Mannich‐type Reactions

XP Mu, YH Li, N Zheng, JY Long, SJ Chen… - Angewandte …, 2021 - Wiley Online Library
A novel method for the concise synthesis of cyclohepta [b] indoles in high yields was
developed. The method involves a visible‐light‐induced, photocatalyzed [2+ 2] …

Thioxanthylium Cations: Highly Reversible Hydrochromic Mate‐rials with Tunable Color and Moisture Sensitivity

MH Chua, XYD Soo, WP Goh, ZM Png… - … –A European Journal, 2022 - Wiley Online Library
Hydrochromic materials, which change color in response to moisture, are highly sought‐
after due to some unique applications such as moisture detection, humidity monitoring, anti …

Organophotocatalytic [2+ 2] Cycloaddition of Electron‐Deficient Styrenes

M Golfmann, L Glagow… - … A European Journal, 2023 - Wiley Online Library
Abstract A visible‐light organophotocatalytic [2+ 2] cycloaddition of electron‐deficient
styrenes is described. Photocatalytic [2+ 2] cycloadditions are typically performed with …

Rapid access to polycyclic thiopyrylium compounds from unfunctionalized aromatics by thia-APEX reaction

KP Kawahara, H Ito, K Itami - Chemical Communications, 2023 - pubs.rsc.org
We developed a sulfur-embedding annulative π-extension (thia-APEX) reaction that could
construct a sulfur-embedding cationic hexagonal aromatic ring, thiopyrylium, onto …

A direct oxidative esterification of aldehydes with alcohols mediated by photochemical C–H bromination

H Ando, S Kodaki, H Takamura, I Kadota… - Organic & Biomolecular …, 2024 - pubs.rsc.org
The photochemical direct esterification of aldehydes with alcohols via in situ-generated acyl-
bromides presented in this report is an attractive complementary addition to hitherto reported …