Carbon–sulfur bond cross-coupling has become more and more attractive as an alternative
protocol to establish carbon–carbon and carbon–heteroatom bonds. Diverse …

This review is an update on development of methodologies towards the synthesis of (hetero)
aryl-substituted heteroarenes through desulfitative direct arylation of C (heteroaryl)-H bonds …

A Pd (II)-catalysed direct desulfitative arylation was realized at the C6-position of the 2-
pyridone scaffold. Aryl sulfonyl chloride was used as an alternative arylating agent. The …

An expeditious synthesis of a wide range of phenanthro [9, 10-b] thiophene derivatives,
which are a class of polyaromatic hydrocarbon (PAH) containing a sulfur atom, is reported …

Palladium-catalyzed reactions using aryl halides as one of the coupling partners represent a
very popular method for generating carbon–carbon bonds. However, such couplings suffer …

This unprecedented review with 322 references provides a critical up-to-date picture of the
Pd-catalysed intermolecular direct C–H bond arylation of heteroarenes with arylating …

The palladium‐catalyzed cross‐dehydrogenative coupling of N‐alkylpyrroles and pyridine N‐
oxides gave the corresponding pyrrolylpyridine N‐oxides. Cu (OAc) 2· H2O as a co‐catalyst …

The direct arylation of N-protected 3-haloindole derivatives with benzenesulfonyl chlorides
as coupling partners using 5 mol% of bis (acetonitrile) dichloropalladium (II) catalyst and …

Palladium-catalyzed decarboxylative arylation is reported using pyrroles N-protected with
the 2-(trimethylsilyl) ethoxymethyl (SEM) group and featuring 2-, 3-, and 4-substituents about …

A series of thienylpyrroles and bithienylpyrroles together with their formyl derivatives 5a–d
were synthesized using commercially or readily available coupling components, through …