Sublimable spin‐crossover complexes: From spin‐state switching to molecular devices

KS Kumar, M Ruben - Angewandte Chemie International …, 2021 - Wiley Online Library
Spin‐crossover (SCO) active transition metal complexes are an important class of
switchable molecular materials due to their bistable spin‐state switching characteristics at or …

The influence of the substrate on the functionality of spin crossover molecular materials

S Yazdani, J Phillips, TK Ekanayaka, R Cheng… - Molecules, 2023 - mdpi.com
Spin crossover complexes are a route toward designing molecular devices with a facile
readout due to the change in conductance that accompanies the change in spin state …

Spin-crossover complexes in direct contact with surfaces

M Gruber, R Berndt - Magnetochemistry, 2020 - mdpi.com
The transfer of the inherent bistability of spin crossover compounds to surfaces has attracted
considerable interest in recent years. The deposition of the complexes on surfaces allows …

Nonvolatile voltage controlled molecular spin-state switching for memory applications

TK Ekanayaka, G Hao, A Mosey, AS Dale, X Jiang… - Magnetochemistry, 2021 - mdpi.com
Nonvolatile, molecular multiferroic devices have now been demonstrated, but it is worth
giving some consideration to the issue of whether such devices could be a competitive …

Design and processing as ultrathin films of a sublimable Iron (II) spin crossover material exhibiting efficient and fast light-induced spin transition

M Gavara-Edo, FJ Valverde-Muñoz… - Chemistry of …, 2023 - ACS Publications
Materials based on spin crossover (SCO) molecules have centered the attention in
molecular magnetism for more than 40 years as they provide unique examples of …

Anomalous light‐induced spin‐state switching for iron (II) spin‐crossover molecules in direct contact with metal surfaces

L Zhang, Y Tong, M Kelai, A Bellec… - Angewandte Chemie …, 2020 - Wiley Online Library
Light‐induced spin‐state switching is one of the most attractive properties of spin‐crossover
materials. In bulk, low‐spin (LS) to high‐spin (HS) conversion via the light‐induced excited …

Quantitative study of the energy changes in voltage-controlled spin crossover molecular thin films

A Mosey, AS Dale, G Hao, A N'Diaye… - The Journal of …, 2020 - ACS Publications
Voltage-controlled nonvolatile isothermal spin state switching of a [Fe {H2B (pz) 2} 2
(bipy)](pz= tris (pyrazol-1–1y)-borohydride, bipy= 2, 2′-bipyridine) film, more than 40 to 50 …

Influence of substrate electronic properties on the integrity and functionality of an adsorbed fe (ii) spin-crossover compound

S Rohlf, J Grunwald, T Jasper-Toennies… - The Journal of …, 2019 - ACS Publications
The bistability of spin-crossover complexes on surfaces is of great interest for potential
applications. Using X-ray absorption spectroscopy, we investigated the properties of [Fe …

Fragmentation and distortion of terpyridine-based spin-crossover complexes on Au (111)

T Knaak, C González, YJ Dappe… - The Journal of …, 2019 - ACS Publications
Spin-crossover complexes are attractive for their spin-switching functionality. However, only
a few compounds have been found to remain intact in direct contact to metal surfaces. For …

Spin state solvomorphism in a series of rare S= 1 manganese (III) complexes

A Barker, CT Kelly, IA Kühne, S Hill, J Krzystek… - Dalton …, 2019 - pubs.rsc.org
Structural, magnetic and spectroscopic data of four complex salts,[Mn (napsal2323)] NTf2,
1,[Mn (napsal2323)] ClO4, 2,[Mn (napsal2323)] BF4, 3 and [Mn (napsal2323)] NO3, 4, of the …