Using redox-active ligands to generate actinide Ligand radical species

SS Galley, SA Pattenaude, D Ray, CA Gaggioli… - Inorganic …, 2021 - ACS Publications
Using a redox-active dioxophenoxazine ligand, DOPO (DOPO= 2, 4, 6, 8-tetra-tert-butyl-1-
oxo-1 H-phenoxazine-9-olate), a family of actinide (U, Th, Np, and Pu) and Hf tris (ligand) …

Synthesis and Characterization of Tris-chelate Complexes for Understanding f-Orbital Bonding in Later Actinides

SS Galley, SA Pattenaude, CA Gaggioli… - Journal of the …, 2019 - ACS Publications
An isostructural family of f-element compounds (Ce, Nd, Sm, Gd; Am, Bk, Cf) of the redox-
active dioxophenoxazine ligand (DOPOq; DOPO= 2, 4, 6, 8-tetra-tert-butyl-1-oxo-1 H …

Uranyl functionalization mediated by redox-active ligands: generation of O–C bonds via acylation

EJ Coughlin, Y Qiao, E Lapsheva, M Zeller… - Journal of the …, 2018 - ACS Publications
A series of uranyl compounds with the redox-active iminoquinone ligand have been
synthesized, and their electronic structures elucidated using multinuclear NMR, EPR …

Chemistry of Complexes of Group 14 Elements Based on Redox-Active Ligands of the o-Iminoquinone Type

MG Chegerev, AV Piskunov - Russian Journal of Coordination Chemistry, 2018 - Springer
Specific features of the synthesis and structures of the complexes of Group 14 elements (Si,
Ge, Sn, Pb) with o-iminoquinone ligands are discussed. The chemical reactions of the above …

Redox non-innocence permits catalytic nitrene carbonylation by (dadi) Ti [double bond, length as m-dash] NAd (Ad= adamantyl)

SP Heins, PT Wolczanski, TR Cundari… - Chemical Science, 2017 - pubs.rsc.org
Application of the diamide, diimine {–CHN (1, 2-C6H4) N (2, 6-iPr2-C6H3)} 2m ((dadi) m)
ligand to titanium provided adducts (dadi) TiLx (1-Lx; Lx= THF, PMe2Ph,(CNMe) 2), which …

Examining the effects of ligand variation on the electronic structure of uranium bis (imido) species

JJ Kiernicki, MG Ferrier… - Journal of the …, 2016 - ACS Publications
Arylazide and diazene activation by highly reduced uranium (IV) complexes bearing
trianionic redox-active pyridine (diimine) ligands,[CpPU (MesPDIMe)] 2 (1-Cp P), Cp* U …

Two lanthanide metal–organic frameworks as sensitive luminescent sensors for the detection of Cr 2+ and Cr 2 O 7 2− in aqueous solutions

XH Huang, L Shi, SM Ying, GY Yan, LH Liu, YQ Sun… - …, 2018 - pubs.rsc.org
Two lanthanide–organic frameworks [Ln (HPIDC)(m-bdc)· 1.5 H2O] n (Ln= Eu 1 or Tb 2;
H3PIDC= 2-(4-pyridyl)-1H-imidazole-4, 5-dicarboxylic acid; m-H2bdc= 1, 3 …

Electronic Structure Description of a Doubly Oxidized Bimetallic Cobalt Complex with Proradical Ligands

RM Clarke, K Hazin, JR Thompson, D Savard… - Inorganic …, 2016 - ACS Publications
The geometric and electronic structure of a doubly oxidized bimetallic Co complex
containing two redox-active salen moieties connected via a 1, 2-phenylene linker was …

Bimetallic iron–iron and iron–zinc complexes of the redox-active ONO pincer ligand

JL Wong, RF Higgins, I Bhowmick, DX Cao… - Chemical …, 2016 - pubs.rsc.org
A new bimetallic platform comprising a six-coordinate Fe (ONO) 2 unit bound to an (ONO) M
(M= Fe, Zn) has been discovered ((ONOcat) H3= bis (3, 5-di-tert-butyl-2-phenol) amine) …

Group 10 bis (iminosemiquinone) complexes: Measurement of singlet–triplet gaps and analysis of the effects of metal and geometry on electronic structure

KM Conner, AL Perugini, M Malabute… - Inorganic …, 2018 - ACS Publications
Bis (iminosemiquinone) complexes of divalent group 10 metals have been described as
having open-shell singlet ground states characteristic of very strong coupling between the …