Catalysts for nitrogen reduction to ammonia
SL Foster, SIP Bakovic, RD Duda, S Maheshwari… - Nature Catalysis, 2018 - nature.com
The production of synthetic ammonia remains dependent on the energy-and capital-
intensive Haber–Bosch process. Extensive research in molecular catalysis has …
intensive Haber–Bosch process. Extensive research in molecular catalysis has …
Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes
Nitrogen fixation, the six-electron/six-proton reduction of N2, to give NH3, is one of the most
challenging and important chemical transformations. Notwithstanding the barriers …
challenging and important chemical transformations. Notwithstanding the barriers …
Single Mo atom supported on defective boron nitride monolayer as an efficient electrocatalyst for nitrogen fixation: a computational study
The production of ammonia (NH3) from molecular dinitrogen (N2) under mild conditions is
one of the most attractive and challenging processes in chemistry. Here by means of density …
one of the most attractive and challenging processes in chemistry. Here by means of density …
Homogeneous catalysis by cobalt and manganese pincer complexes
A Mukherjee, D Milstein - ACS Catalysis, 2018 - ACS Publications
Homogeneous catalysis of organic transformations by metal complexes has been mostly
based on complexes of noble metals. In recent years, tremendous progress has been made …
based on complexes of noble metals. In recent years, tremendous progress has been made …
Near ambient N2 fixation on solid electrodes versus enzymes and homogeneous catalysts
Abstract The Mo/Fe nitrogenase enzyme is unique in its ability to efficiently reduce
dinitrogen to ammonia at atmospheric pressures and room temperature. Should an artificial …
dinitrogen to ammonia at atmospheric pressures and room temperature. Should an artificial …
Nitrogen fixation reaction derived from nanostructured catalytic materials
S Wang, F Ichihara, H Pang, H Chen… - Advanced Functional …, 2018 - Wiley Online Library
An efficient nitrogen fixation reaction is highly desirable for obtaining the essential chemicals
and energy carriers but remains a challenge due to the strong nonpolar bonding and …
and energy carriers but remains a challenge due to the strong nonpolar bonding and …
Double-atom catalysts: transition metal dimer-anchored C 2 N monolayers as N 2 fixation electrocatalysts
Nitrogen fixation is one of the most essential processes in chemistry. Developing more
effective nitrogen fixation systems to catalyze the reaction under mild conditions is one of the …
effective nitrogen fixation systems to catalyze the reaction under mild conditions is one of the …
Comprehensive insights into synthetic nitrogen fixation assisted by molecular catalysts under ambient or mild conditions
Y Tanabe, Y Nishibayashi - Chemical Society Reviews, 2021 - pubs.rsc.org
N2 is fixed as NH3 industrially by the Haber–Bosch process under harsh conditions,
whereas biological nitrogen fixation is achieved under ambient conditions, which has …
whereas biological nitrogen fixation is achieved under ambient conditions, which has …
Examining the relationship between coordination mode and reactivity of dinitrogen
RJ Burford, MD Fryzuk - Nature Reviews Chemistry, 2017 - nature.com
Molecular nitrogen (N2) is the most abundant gas in Earth's atmosphere, but its low reactivity
has hampered its use as a precursor to higher value nitrogen-containing compounds …
has hampered its use as a precursor to higher value nitrogen-containing compounds …
Atomically embedded asymmetrical dual-metal dimers on N-doped graphene for ultra-efficient nitrogen reduction reaction
The atomically dispersed metal species on nitrogen-doped graphene nanosheets have
exhibited impressive catalytic properties towards oxygen evolution, oxygen reduction and …
exhibited impressive catalytic properties towards oxygen evolution, oxygen reduction and …