Design and applications of water-soluble coordination cages

EG Percástegui, TK Ronson, JR Nitschke - Chemical Reviews, 2020 - ACS Publications
Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …

Metal–photoswitch friendship: from photochromic complexes to functional materials

GC Thaggard, J Haimerl, KC Park, J Lim… - Journal of the …, 2022 - ACS Publications
Cooperative metal–photoswitch interfaces comprise an application-driven field which is
based on strategic coupling of metal cations and organic photochromic molecules to …

Disequilibrating azobenzenes by visible-light sensitization under confinement

J Gemen, JR Church, TP Ruoko, N Durandin… - Science, 2023 - science.org
Photoisomerization of azobenzenes from their stable E isomer to the metastable Z state is
the basis of numerous applications of these molecules. However, this reaction typically …

Smart photochromic materials triggered with visible light

AL Leistner, ZL Pianowski - European Journal of Organic …, 2022 - Wiley Online Library
Molecular photoswitches reversibly convert the energy of light into a variety of structural
changes at the molecular level. They can be integrated into smart materials with broad …

Molecular photoswitching in confined spaces

AB Grommet, LM Lee, R Klajn - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus In nature, light is harvested by photoactive proteins to drive a range of biological
processes, including photosynthesis, phototaxis, vision, and ultimately life …

Arylazopyrazoles for long-term thermal energy storage and optically triggered heat release below 0° C

MA Gerkman, RSL Gibson, J Calbo, Y Shi… - Journal of the …, 2020 - ACS Publications
Arylazopyrazole derivatives based on four core structures (4pzMe, 3pzH, 4pzH, and 4pzH-
F2) and functionalized with a dodecanoate group were demonstrated to store thermal …

Sunlight-activated phase change materials for controlled heat storage and triggered release

Y Shi, MA Gerkman, Q Qiu, S Zhang… - Journal of Materials …, 2021 - pubs.rsc.org
We report the design of photo-responsive organic phase change materials that can absorb
filtered solar radiation to store both latent heat and photon energy via simultaneous phase …

Toward controlled thermal energy storage and release in organic phase change materials

MA Gerkman, GGD Han - Joule, 2020 - cell.com
Grace Han was born in South Korea and graduated from POSTECH with a BS in Chemistry.
She obtained her PhD in Chemistry at MIT in 2015 and joined the Department of Materials …

Altering the properties of spiropyran switches using coordination cages with different symmetries

J Wang, L Avram, Y Diskin-Posner… - Journal of the …, 2022 - ACS Publications
Molecular confinement effects can profoundly alter the physicochemical properties of the
confined species. A plethora of organic molecules were encapsulated within the cavities of …

Stimuli-responsive organic phase change materials: molecular designs and applications in energy storage

M Le, GGD Han - Accounts of Materials Research, 2022 - ACS Publications
Conspectus Achieving a stable latent heat storage over a wide temperature range and a
long period of time as well as accomplishing a controlled heat release from conventional …