Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

How catalysts and experimental conditions determine the selective hydroconversion of furfural and 5-hydroxymethylfurfural

S Chen, R Wojcieszak, F Dumeignil, E Marceau… - Chemical …, 2018 - ACS Publications
Furfural and 5-hydroxymethylfurfural stand out as bridges connecting biomass raw materials
to the biorefinery industry. Their reductive transformations by hydroconversion are key …

[HTML][HTML] Addressing complexity in catalyst design: From volcanos and scaling to more sophisticated design strategies

SM Stratton, S Zhang, MM Montemore - Surface Science Reports, 2023 - Elsevier
Volcano plots and scaling relations are commonly used to design catalysts and understand
catalytic behavior. These plots are a useful tool due to their robust and simple analysis of …

Molecular approaches to heterogeneous catalysis

F Zaera - Coordination Chemistry Reviews, 2021 - Elsevier
In most applications in industry involving catalysis, heterogeneous catalysts are preferred
over their homogeneous counterparts when available. However, the former cannot be easily …

Controlling selectivity in unsaturated aldehyde hydrogenation using single-site alloy catalysts

Y Cao, B Chen, J Guerrero-Sánchez, I Lee, X Zhou… - ACS …, 2019 - ACS Publications
Selectivity in catalysis is key to many industrial processes, yet it is often difficult to control.
One promising approach is to use so-called single-atom catalysts, whereby one catalytic …

Sub-monolayer control of mixed-oxide support composition in catalysts via atomic layer deposition: selective hydrogenation of cinnamaldehyde promoted by (SiO2 …

Z Weng, F Zaera - ACS Catalysis, 2018 - ACS Publications
Alumina-supported platinum catalysts have been modified with silicon oxide thin films grown
using atomic layer deposition (ALD) in order to tune the acid–base and electronic properties …

Surface dipole control of liquid crystal alignment

JJ Schwartz, AM Mendoza, N Wattanatorn… - Journal of the …, 2016 - ACS Publications
Detailed understanding and control of the intermolecular forces that govern molecular
assembly are necessary to engineer structure and function at the nanoscale. Liquid crystal …

Toward Low-Temperature Heterogeneous Hydrogenation of Carbonyl Compounds: Molecular Systems for Reversible Hydrogen Storage

S Schauermann - ACS Catalysis, 2023 - ACS Publications
Hydrogenation of carbonyl compounds to alcohols is an important step in many
technological applications, including the emerging molecular systems for reversable …

Selective furfural hydrogenolysis towards 2-methylfuran by controlled poisoning of Cu–Co catalysts with chlorine

A Barranca, I Agirrezabal-Tellería… - Reaction Chemistry & …, 2023 - pubs.rsc.org
The selective hydrogenolysis of C–OH bond without the hydrogenation of the furan ring is an
important step in the valorization of relevant biomass-derived platform chemicals. Herein, we …

Microkinetic Modeling of Benzyl Alcohol Oxidation on Carbon‐Supported Palladium Nanoparticles

A Savara, I Rossetti, CE Chan‐Thaw, L Prati… - …, 2016 - Wiley Online Library
Six products are formed from benzyl alcohol oxidation over Pd nanoparticles using O2 as
the oxidant: benzaldehyde, toluene, benzyl ether, benzene, benzoic acid, and benzyl …