3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions

S Rej, A Das, N Chatani - Coordination Chemistry Reviews, 2021 - Elsevier
In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

Copper-catalyzed electrochemical C–H amination of arenes with secondary amines

QL Yang, XY Wang, JY Lu, LP Zhang… - Journal of the …, 2018 - ACS Publications
Electrochemical oxidation represents an environmentally friendly solution to conventional
methods that require caustic stoichiometric chemical oxidants. However, C–H …

Catalytic methods for aromatic C–H amination: an ideal strategy for nitrogen-based functional molecules

J Jiao, K Murakami, K Itami - ACS Catalysis, 2016 - ACS Publications
Transformations of aromatic compounds into the corresponding amines, amides, and imides
through carbon–hydrogen (C–H) bond functionalization represent one of the most step-and …

Recent advances in copper-mediated chelation-assisted functionalization of unactivated C–H bonds

WH Rao, BF Shi - Organic Chemistry Frontiers, 2016 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds has recently emerged as a
powerful strategy for the construction of carbon–carbon and carbon–heteroatom bonds …

Syntheses and transformations of sulfoximines

W Zheng, X Chen, F Chen, Z He… - The Chemical Record, 2021 - Wiley Online Library
Sulfoximines are widely used as medicines, agricultural chemicals, chiral precursors, and
chiral ligands in asymmetric synthesis, as well as pivotal intermediates for the construction of …

N− H and C− H functionalization of sulfoximine: recent advancement and prospects

P Ghosh, B Ganguly, S Das - Asian Journal of Organic …, 2020 - Wiley Online Library
Sulfoximine and its congeners are a versatile class of structural motifs widely found in a
plethora of pharmaceutical compounds and crop protection industries due to their …

Ligand-to-copper charge-transfer-enabled C–H sulfoximination of Arenes

W Su, P Xu, R Petzold, J Yan, T Ritter - Organic Letters, 2023 - ACS Publications
Herein, we report a photoinduced sulfoximine-to-copper charge-transfer-enabled generation
of sulfoximinyl radicals directly from NH-sulfoximines for C–H sulfoximination of arenes via …

Copper-mediated amination of aryl C–H bonds with the direct use of aqueous ammonia via a disproportionation pathway

H Kim, J Heo, J Kim, MH Baik… - Journal of the American …, 2018 - ACS Publications
The direct amination of C–H bonds with ammonia is a challenge in synthetic chemistry.
Herein, we present a copper-mediated approach that enables a chelation-assisted aromatic …

Nickel-Catalyzed Direct Thiolation of C(sp3)–H Bonds in Aliphatic Amides

X Wang, R Qiu, C Yan, VP Reddy, L Zhu, X Xu… - Organic …, 2015 - ACS Publications
Nickel-Catalyzed Direct Thiolation of C(sp3)–H Bonds in Aliphatic Amides | Organic Letters
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